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Surface plasmon observed for carbon nanotubes

Abstract

This paper presents parallel electron energy loss spectra (PEELS) results, obtained for individual carbon nanotubes, using nanoprobe techniques (1-2 nm diameter electron beam), energy resolution 0.5 eV and collection times of 4-25 sec. The aim was to use a nanoprobe to compare PEELS spectra from different parts of a tube, in order to search for variations in sp{sup 2}/sp{sup 3} bonding ratios as well as to look for orientation dependent plasmon and core-loss phenomena. It also seemed interesting to compare results for nanotubes with those for other varieties of graphitized carbons. The most interesting result so far was the appearance of a 15 eV plasmon peak, which appeared only for tubes containing {<=} about 12 graphite-like layers. This peak did not shift significantly with tube size. A low-loss peaks at 6 eV of variable relative intensity was also observed this peak was relatively very weak for amorphous tubes; it appears to be characteristic of graphite-like layers, as found for nanotubes and, of course, graphite itself. This paper is restricted to discussion of the low-loss results. The experimental techniques are first described, including some details of the methods which may be used to disperse and support sooty carbons for high-resolution transmission  More>>
Authors:
Bursill, L A; Stadelmann, P A; [1]  Peng, J L; Prawer, S [2] 
  1. Ecole Polytechnique Federale, Lausanne (Switzerland)
  2. Melbourne Univ., Parkville, VIC (Australia). School of Physics
Publication Date:
Dec 31, 1993
Product Type:
Technical Report
Report Number:
UM-P-93/73
Reference Number:
SCA: 665200; PA: AIX-25:076884; EDB-94:171845; ERA-20:002345; SN: 94001283418
Resource Relation:
Other Information: PBD: [1993]
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; CARBON; GRAPHITIZATION; PLASMONS; ENERGY LOSSES; TRANSMISSION ELECTRON MICROSCOPY; CRYSTAL GROWTH; ELECTRON MICROPROBE ANALYSIS; ELECTRON SPECTRA; EV RANGE 01-10; EV RANGE 10-100; EXPERIMENTAL DATA; FULLERENES; HYPERFINE STRUCTURE; 665200; SOLID-STATE PLASMA
Sponsoring Organizations:
Australian Research Council, Canberra, ACT (Australia); Swiss National Science Foundation, Bern (Switzerland)
OSTI ID:
10195602
Research Organizations:
Melbourne Univ., Parkville, VIC (Australia). School of Physics
Country of Origin:
Australia
Language:
English
Other Identifying Numbers:
Other: ON: DE95607769; TRN: AU9413967076884
Availability:
OSTI; NTIS (US Sales Only); INIS
Submitting Site:
INIS
Size:
15 p.
Announcement Date:
Jul 08, 2005

Citation Formats

Bursill, L A, Stadelmann, P A, Peng, J L, and Prawer, S. Surface plasmon observed for carbon nanotubes. Australia: N. p., 1993. Web.
Bursill, L A, Stadelmann, P A, Peng, J L, &amp; Prawer, S. Surface plasmon observed for carbon nanotubes. Australia.
Bursill, L A, Stadelmann, P A, Peng, J L, and Prawer, S. 1993. "Surface plasmon observed for carbon nanotubes." Australia.
@misc{etde_10195602,
title = {Surface plasmon observed for carbon nanotubes}
author = {Bursill, L A, Stadelmann, P A, Peng, J L, and Prawer, S}
abstractNote = {This paper presents parallel electron energy loss spectra (PEELS) results, obtained for individual carbon nanotubes, using nanoprobe techniques (1-2 nm diameter electron beam), energy resolution 0.5 eV and collection times of 4-25 sec. The aim was to use a nanoprobe to compare PEELS spectra from different parts of a tube, in order to search for variations in sp{sup 2}/sp{sup 3} bonding ratios as well as to look for orientation dependent plasmon and core-loss phenomena. It also seemed interesting to compare results for nanotubes with those for other varieties of graphitized carbons. The most interesting result so far was the appearance of a 15 eV plasmon peak, which appeared only for tubes containing {<=} about 12 graphite-like layers. This peak did not shift significantly with tube size. A low-loss peaks at 6 eV of variable relative intensity was also observed this peak was relatively very weak for amorphous tubes; it appears to be characteristic of graphite-like layers, as found for nanotubes and, of course, graphite itself. This paper is restricted to discussion of the low-loss results. The experimental techniques are first described, including some details of the methods which may be used to disperse and support sooty carbons for high-resolution transmission electron microscopy. The results are then presented, followed by an interpretation of all the low-loss PEELS results, including those of the other authors. 14 refs., 2 figs.}
place = {Australia}
year = {1993}
month = {Dec}
}