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Surface analysis in steel nitrides by using Moessbauer spectroscopy; Analise de superficie em acos nitretados por espectroscopia Moessbauer

Abstract

The formation of iron nitride layer at low temperatures, 600-700 K, by Moessbauer spectroscopy is studied. These layers were obtained basically through two different processes: ion nitriding and ammonia gas nitriding. A preliminary study about post-discharge nitriding was made using discharge in hollow cathode as well as microwave excitation. The assembly of these chambers is also described. The analysis of the nitrided samples was done by CEMS and CXMS, aided by optical microscopy, and the CEMS and CXMS detectors were constructed by ourselves. We also made a brief study about these detectors, testing as acetone as the mixture 80% He+10% C H{sub 4} as detection gases for the use of CEMS. The surface analysis of the samples showed that in the ammonia gas process nitriding the nitrided layer starts by the superficial formation of an iron nitride rich nitrogen. By thermal evolution this nitride promotes the diffusion of nitrogen and the formation of other more stable nitrides. (author).
Publication Date:
Jul 01, 1991
Product Type:
Thesis/Dissertation
Report Number:
INIS-BR-3336
Reference Number:
SCA: 665100; PA: AIX-25:042618; EDB-94:092228; ERA-19:023014; NTS-94:023629; SN: 94001032394
Resource Relation:
Other Information: TH: Tese (M.Sc.).; PBD: Jul 1991
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; IRON NITRIDES; MOESSBAUER EFFECT; OPTICAL MICROSCOPY; STEELS; STRUCTURAL CHEMICAL ANALYSIS; 665100; NUCLEAR TECHNIQUES IN CONDENSED MATTER PHYSICS
OSTI ID:
10157183
Research Organizations:
Santa Catarina Univ., Florianopolis, SC (Brazil)
Country of Origin:
Brazil
Language:
Portuguese
Other Identifying Numbers:
Other: ON: DE94627032; TRN: BR9432057042618
Availability:
OSTI; NTIS (US Sales Only); INIS
Submitting Site:
INIS
Size:
168 p.
Announcement Date:
Jul 06, 2005

Citation Formats

Figueiredo, R.S. de. Surface analysis in steel nitrides by using Moessbauer spectroscopy; Analise de superficie em acos nitretados por espectroscopia Moessbauer. Brazil: N. p., 1991. Web.
Figueiredo, R.S. de. Surface analysis in steel nitrides by using Moessbauer spectroscopy; Analise de superficie em acos nitretados por espectroscopia Moessbauer. Brazil.
Figueiredo, R.S. de. 1991. "Surface analysis in steel nitrides by using Moessbauer spectroscopy; Analise de superficie em acos nitretados por espectroscopia Moessbauer." Brazil.
@misc{etde_10157183,
title = {Surface analysis in steel nitrides by using Moessbauer spectroscopy; Analise de superficie em acos nitretados por espectroscopia Moessbauer}
author = {Figueiredo, R.S. de}
abstractNote = {The formation of iron nitride layer at low temperatures, 600-700 K, by Moessbauer spectroscopy is studied. These layers were obtained basically through two different processes: ion nitriding and ammonia gas nitriding. A preliminary study about post-discharge nitriding was made using discharge in hollow cathode as well as microwave excitation. The assembly of these chambers is also described. The analysis of the nitrided samples was done by CEMS and CXMS, aided by optical microscopy, and the CEMS and CXMS detectors were constructed by ourselves. We also made a brief study about these detectors, testing as acetone as the mixture 80% He+10% C H{sub 4} as detection gases for the use of CEMS. The surface analysis of the samples showed that in the ammonia gas process nitriding the nitrided layer starts by the superficial formation of an iron nitride rich nitrogen. By thermal evolution this nitride promotes the diffusion of nitrogen and the formation of other more stable nitrides. (author).}
place = {Brazil}
year = {1991}
month = {Jul}
}