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Photoluminescent samarium octamolybdate

Abstract

The structure of bis(hexaaquasamarium) octamolybdate hexahydrate, Sm{sub 2}(H{sub 2}O){sub 12}[Mo{sub 8}O{sub 27}].6H{sub 2}O, consists of [(Mo{sub 8}O{sub 27}){sup 6-}]{sub {infinity}} chains supported by hydrated Sm{sup 3+} cations. Sm{sup 3+} has tricapped trigonal prismatic coordination with Sm-O distances of 2.38-2.66 A. Mo-O distances in the octamolybdate unit are 1.68-2.49 A. (orig.).
Authors:
Yamase, T; [1]  Ozeki, T; [1]  Kawashima, I [1] 
  1. Tokyo Inst. of Tech., Yokohama (Japan). Research Lab. of Resources Utilization
Publication Date:
Apr 15, 1995
Product Type:
Journal Article
Reference Number:
SCA: 360602; PA: AIX-26:059248; EDB-95:130774; SN: 95001462121
Resource Relation:
Journal Name: Acta Crystallographica. Section C, Crystal Structure Communications; Journal Volume: 51; Journal Issue: 4; Other Information: PBD: 15 Apr 1995
Subject:
36 MATERIALS SCIENCE; MOLYBDATES; CRYSTAL STRUCTURE; SAMARIUM COMPOUNDS; X-RAY DIFFRACTION
OSTI ID:
101563
Country of Origin:
Denmark
Language:
English
Other Identifying Numbers:
Journal ID: ACSCEE; ISSN 0108-2701; TRN: DK95FD228059248
Submitting Site:
DKN
Size:
pp. 545-546
Announcement Date:
Oct 06, 1995

Citation Formats

Yamase, T, Ozeki, T, and Kawashima, I. Photoluminescent samarium octamolybdate. Denmark: N. p., 1995. Web. doi:10.1107/S0108270194012205.
Yamase, T, Ozeki, T, & Kawashima, I. Photoluminescent samarium octamolybdate. Denmark. https://doi.org/10.1107/S0108270194012205
Yamase, T, Ozeki, T, and Kawashima, I. 1995. "Photoluminescent samarium octamolybdate." Denmark. https://doi.org/10.1107/S0108270194012205.
@misc{etde_101563,
title = {Photoluminescent samarium octamolybdate}
author = {Yamase, T, Ozeki, T, and Kawashima, I}
abstractNote = {The structure of bis(hexaaquasamarium) octamolybdate hexahydrate, Sm{sub 2}(H{sub 2}O){sub 12}[Mo{sub 8}O{sub 27}].6H{sub 2}O, consists of [(Mo{sub 8}O{sub 27}){sup 6-}]{sub {infinity}} chains supported by hydrated Sm{sup 3+} cations. Sm{sup 3+} has tricapped trigonal prismatic coordination with Sm-O distances of 2.38-2.66 A. Mo-O distances in the octamolybdate unit are 1.68-2.49 A. (orig.).}
doi = {10.1107/S0108270194012205}
journal = []
issue = {4}
volume = {51}
journal type = {AC}
place = {Denmark}
year = {1995}
month = {Apr}
}