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Formation of fine palladium particles from palladium sulfate aqueous solution by gamma-ray irradiation as observed by electronic absorption spectroscopy and dynamic light scattering

Abstract

To find a way of probing the coagulation of metal particles formed by the irradiation of metallic ion solution without surfactant, palladium sulfate aqueous solution was irradiated with gamma rays (11.2kGy/h, 10kGy) and turbidity change of the solution after irradiation was followed by optical density at 700nm using a UV-visible spectrophotometer. The particle diameter distribution was monitored by dynamic light scattering. The results indicate that the turbidity decreased monotonously, and that there are major peaks in the distributions, one with diameters in the 400-800nm region and the other with diameters in the 1500-2500nm. The density of the particles seems to be smaller than that of bulk palladium metal. Similar experiments were carried out on palladium-silver sulfate solution. (author).
Authors:
Jonah, C D; [1]  Hatada, Motoyoshi
  1. Argonne National Lab., IL (United States)
Publication Date:
Jan 01, 1994
Product Type:
Technical Report
Report Number:
JAERI-M-93-248
Reference Number:
SCA: 665300; PA: JPN-94:004100; EDB-94:085700; ERA-19:023068; NTS-95:001343; SN: 94001212190
Resource Relation:
Other Information: PBD: Jan 1994
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; PALLADIUM; GAMMA RADIATION; IRRADIATION; SULFATES; PARTICLES; ABSORPTION SPECTRA; SCATTERING; AQUEOUS SOLUTIONS; PARTICLE SIZE; 665300; INTERACTIONS BETWEEN BEAMS AND CONDENSED MATTER
OSTI ID:
10156013
Research Organizations:
Japan Atomic Energy Research Inst., Tokyo (Japan)
Country of Origin:
Japan
Language:
English
Other Identifying Numbers:
Other: ON: DE94770602; TRN: JP9404100
Availability:
OSTI; NTIS; INIS
Submitting Site:
JPN
Size:
38 p.
Announcement Date:
Jul 06, 2005

Citation Formats

Jonah, C D, and Hatada, Motoyoshi. Formation of fine palladium particles from palladium sulfate aqueous solution by gamma-ray irradiation as observed by electronic absorption spectroscopy and dynamic light scattering. Japan: N. p., 1994. Web.
Jonah, C D, & Hatada, Motoyoshi. Formation of fine palladium particles from palladium sulfate aqueous solution by gamma-ray irradiation as observed by electronic absorption spectroscopy and dynamic light scattering. Japan.
Jonah, C D, and Hatada, Motoyoshi. 1994. "Formation of fine palladium particles from palladium sulfate aqueous solution by gamma-ray irradiation as observed by electronic absorption spectroscopy and dynamic light scattering." Japan.
@misc{etde_10156013,
title = {Formation of fine palladium particles from palladium sulfate aqueous solution by gamma-ray irradiation as observed by electronic absorption spectroscopy and dynamic light scattering}
author = {Jonah, C D, and Hatada, Motoyoshi}
abstractNote = {To find a way of probing the coagulation of metal particles formed by the irradiation of metallic ion solution without surfactant, palladium sulfate aqueous solution was irradiated with gamma rays (11.2kGy/h, 10kGy) and turbidity change of the solution after irradiation was followed by optical density at 700nm using a UV-visible spectrophotometer. The particle diameter distribution was monitored by dynamic light scattering. The results indicate that the turbidity decreased monotonously, and that there are major peaks in the distributions, one with diameters in the 400-800nm region and the other with diameters in the 1500-2500nm. The density of the particles seems to be smaller than that of bulk palladium metal. Similar experiments were carried out on palladium-silver sulfate solution. (author).}
place = {Japan}
year = {1994}
month = {Jan}
}