Abstract
Room-temperature molten salts have been studied as electrolytes for batteries or as solvents for electrochemical reactions (example: metal coating). They can also be used as solvents for transition metal catalytic cationic complexes (examples: nickel complexes for olefin dimerization, Ziegler-Natta titanium complexes for ethylene polymerization). They are particularly interesting because of their non-miscibility with non functionalized olefins and in consequence they can be used in two-phase catalysis. For this purpose, the properties expected from these media as well as their compositions are different from those expected for electrochemistry. We have studied mixtures of dialkylimidazolium chloride with ethylaluminium chloride compounds like Et{sub x}AlCl{sub (3-x)} (with x = 0, 1, 2 or 3). The catalytic reaction we were interested in is the olefin metathesis by tungsten complexes.
Citation Formats
Di Marco-van-Tiggelen, F.
Catalysis in non aqueous ionic medium. Metathesis of olefins by tungsten complexes.
France: N. p.,
1994.
Web.
Di Marco-van-Tiggelen, F.
Catalysis in non aqueous ionic medium. Metathesis of olefins by tungsten complexes.
France.
Di Marco-van-Tiggelen, F.
1994.
"Catalysis in non aqueous ionic medium. Metathesis of olefins by tungsten complexes."
France.
@misc{etde_10155909,
title = {Catalysis in non aqueous ionic medium. Metathesis of olefins by tungsten complexes}
author = {Di Marco-van-Tiggelen, F}
abstractNote = {Room-temperature molten salts have been studied as electrolytes for batteries or as solvents for electrochemical reactions (example: metal coating). They can also be used as solvents for transition metal catalytic cationic complexes (examples: nickel complexes for olefin dimerization, Ziegler-Natta titanium complexes for ethylene polymerization). They are particularly interesting because of their non-miscibility with non functionalized olefins and in consequence they can be used in two-phase catalysis. For this purpose, the properties expected from these media as well as their compositions are different from those expected for electrochemistry. We have studied mixtures of dialkylimidazolium chloride with ethylaluminium chloride compounds like Et{sub x}AlCl{sub (3-x)} (with x = 0, 1, 2 or 3). The catalytic reaction we were interested in is the olefin metathesis by tungsten complexes.}
place = {France}
year = {1994}
month = {Jan}
}
title = {Catalysis in non aqueous ionic medium. Metathesis of olefins by tungsten complexes}
author = {Di Marco-van-Tiggelen, F}
abstractNote = {Room-temperature molten salts have been studied as electrolytes for batteries or as solvents for electrochemical reactions (example: metal coating). They can also be used as solvents for transition metal catalytic cationic complexes (examples: nickel complexes for olefin dimerization, Ziegler-Natta titanium complexes for ethylene polymerization). They are particularly interesting because of their non-miscibility with non functionalized olefins and in consequence they can be used in two-phase catalysis. For this purpose, the properties expected from these media as well as their compositions are different from those expected for electrochemistry. We have studied mixtures of dialkylimidazolium chloride with ethylaluminium chloride compounds like Et{sub x}AlCl{sub (3-x)} (with x = 0, 1, 2 or 3). The catalytic reaction we were interested in is the olefin metathesis by tungsten complexes.}
place = {France}
year = {1994}
month = {Jan}
}