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The isotope dilution mass spectrometry with {sup 233}U as a single internal standard

Abstract

The isotope dilution mass spectrometry with {sup 233}U as a single internal standard has been developed. It can be used to determine the abundant ratio precisely in the uranium sample. It is an absolute measurement method based on gravimetry. The {sup 233}U and measured uranium sample are gravimetrically mixed. Then, the R{sub 58} ({sup 235}U/{sup 238}U) and R{sub 38}({sup 233}U/{sup 238}U) in the mixture are simultaneously measured, and the R{sub 38} is taken as internal reference standard. By using the iteration operation the R{sub 58} can gradually reach to its true value. The total uncertainty of the method for measuring R{sub 58} is 0.15%. In addition, it has many advantages, such as, the measured external precision can be better than 0.02%.
Authors:
Maolin, Chen; Shugui, Yang; Jinhua, Chen; Zhonggang, Zhao [1] 
  1. Sichuan Research Inst. of Materials and Technology, Chengdu (China)
Publication Date:
Mar 01, 1993
Product Type:
Technical Report
Report Number:
CNIC-00713; SRIMT-0006.
Reference Number:
SCA: 400101; PA: AIX-25:035644; EDB-94:082275; ERA-19:019113; NTS-94:022144; SN: 94001206473
Resource Relation:
Other Information: PBD: Mar 1993
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; URANIUM 233; ISOTOPE DILUTION; MASS SPECTROSCOPY; CALIBRATION STANDARDS; ISOTOPE RATIO; MIXTURES; URANIUM 235; URANIUM 238; 400101; ACTIVATION, NUCLEAR REACTION, RADIOMETRIC, AND RADIOCHEMICAL PROCEDURES
OSTI ID:
10153056
Research Organizations:
China Nuclear Information Centre, Beijing, BJ (China)
Country of Origin:
China
Language:
Chinese
Other Identifying Numbers:
Other: ON: DE94624076; ISBN 7-5022-0867-4; TRN: CN9400349035644
Availability:
OSTI; NTIS (US Sales Only); INIS
Submitting Site:
INIS
Size:
8 p.
Announcement Date:
Jul 05, 2005

Citation Formats

Maolin, Chen, Shugui, Yang, Jinhua, Chen, and Zhonggang, Zhao. The isotope dilution mass spectrometry with {sup 233}U as a single internal standard. China: N. p., 1993. Web.
Maolin, Chen, Shugui, Yang, Jinhua, Chen, & Zhonggang, Zhao. The isotope dilution mass spectrometry with {sup 233}U as a single internal standard. China.
Maolin, Chen, Shugui, Yang, Jinhua, Chen, and Zhonggang, Zhao. 1993. "The isotope dilution mass spectrometry with {sup 233}U as a single internal standard." China.
@misc{etde_10153056,
title = {The isotope dilution mass spectrometry with {sup 233}U as a single internal standard}
author = {Maolin, Chen, Shugui, Yang, Jinhua, Chen, and Zhonggang, Zhao}
abstractNote = {The isotope dilution mass spectrometry with {sup 233}U as a single internal standard has been developed. It can be used to determine the abundant ratio precisely in the uranium sample. It is an absolute measurement method based on gravimetry. The {sup 233}U and measured uranium sample are gravimetrically mixed. Then, the R{sub 58} ({sup 235}U/{sup 238}U) and R{sub 38}({sup 233}U/{sup 238}U) in the mixture are simultaneously measured, and the R{sub 38} is taken as internal reference standard. By using the iteration operation the R{sub 58} can gradually reach to its true value. The total uncertainty of the method for measuring R{sub 58} is 0.15%. In addition, it has many advantages, such as, the measured external precision can be better than 0.02%.}
place = {China}
year = {1993}
month = {Mar}
}