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Phase diagrams for the binary systems NdCl{sub 3}-LiCl and PrCl{sub 3}-LiCl

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Abstract

Equilibrium diagrams for the binary systems NdCl{sub 3}-LiCl and PrCl{sub 3}-LiCl were studied over the temperature range 200-800degC by differential thermal analysis techniques. A peritectic was observed in the NdCl{sub 3}-LiCl system. The eutectic occurred at 456{+-}2degC and 30.7mol% NdCl{sub 3} and the peritectic occurred at 467{+-}1degC. A single eutectic was observed in the PrCl{sub 3}-LiCl system with no evidence of solid solution or compound formation. The eutectic occurred at 464{+-}1degC and 30.6mol% PrCl{sub 3} in the PrCl{sub 3}-LiCl system. Binary phase diagrams for the two systems were proposed from the DTA results. (author)
Authors:
Kim, Ik-Soo; [1]  Okamoto, Yoshihiro
  1. Korea Atomic Energy Research Institute, Taejon (Korea, Republic of)
Publication Date:
Apr 01, 1999
Product Type:
Technical Report
Report Number:
JAERI-Research-99-033
Reference Number:
SCA: 400201; PA: JPN-99:050385; EDB-99:080534; SN: 99002124415
Resource Relation:
Other Information: PBD: Apr 1999
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; MOLTEN SALTS; NEODYMIUM CHLORIDES; LITHIUM CHLORIDES; PRASEODYMIUM CHLORIDES; TEMPERATURE RANGE 0400-1000 K; DIFFERENTIAL THERMAL ANALYSIS; X-RAY DIFFRACTION; EUTECTICS; PHASE DIAGRAMS; 400201; CHEMICAL AND PHYSICOCHEMICAL PROPERTIES
OSTI ID:
10147618
Research Organizations:
Japan Atomic Energy Research Inst., Tokyo (Japan)
Country of Origin:
Japan
Language:
English
Other Identifying Numbers:
Other: ON: DE99760438; TRN: JP9950385
Availability:
OSTI; NTIS (US Sales Only)
Submitting Site:
JPN
Size:
22 p.
Announcement Date:
Sep 10, 1999

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Citation Formats

Kim, Ik-Soo, and Okamoto, Yoshihiro. Phase diagrams for the binary systems NdCl{sub 3}-LiCl and PrCl{sub 3}-LiCl. Japan: N. p., 1999. Web.
Kim, Ik-Soo, & Okamoto, Yoshihiro. Phase diagrams for the binary systems NdCl{sub 3}-LiCl and PrCl{sub 3}-LiCl. Japan.
Kim, Ik-Soo, and Okamoto, Yoshihiro. 1999. "Phase diagrams for the binary systems NdCl{sub 3}-LiCl and PrCl{sub 3}-LiCl." Japan.
@misc{etde_10147618,
title = {Phase diagrams for the binary systems NdCl{sub 3}-LiCl and PrCl{sub 3}-LiCl}
 author = {Kim, Ik-Soo, and Okamoto, Yoshihiro}
 abstractNote = {Equilibrium diagrams for the binary systems NdCl{sub 3}-LiCl and PrCl{sub 3}-LiCl were studied over the temperature range 200-800degC by differential thermal analysis techniques. A peritectic was observed in the NdCl{sub 3}-LiCl system. The eutectic occurred at 456{+-}2degC and 30.7mol% NdCl{sub 3} and the peritectic occurred at 467{+-}1degC. A single eutectic was observed in the PrCl{sub 3}-LiCl system with no evidence of solid solution or compound formation. The eutectic occurred at 464{+-}1degC and 30.6mol% PrCl{sub 3} in the PrCl{sub 3}-LiCl system. Binary phase diagrams for the two systems were proposed from the DTA results. (author)}
 place = {Japan}
 year = {1999}
 month = {Apr}
 }