Abstract
The original method of interpretation together with its theoretical foundations is developed, making it possible to use location and direction of the double-double (tetrad) effect within the Ln and An series to determine the coordination number (CN) complexes of the f-block elements. The method is applied for potentiometric and radiometric equilibrium studies. It has been pointed and that the decisive factor for the direction of the double-double effect in the case of the Gibbs energy variations is a difference in the CN of the f-element ion between the reaction product complex and that for the reaction substrate the ``regular`` effect for a given tetrad is accompanied by decrease in the CN while the ``reverse`` effect by increase in the CN. (author). 122 refs, 5 tabs, 8 figs.
Mioduski, T
[1]
- Institute of Nuclear Chemistry and Technology, Warsaw (Poland)
Citation Formats
Mioduski, T.
Double-double effect and coordination number; Efekt podwojnie-podwojny a liczba koordynacji.
Poland: N. p.,
1992.
Web.
Mioduski, T.
Double-double effect and coordination number; Efekt podwojnie-podwojny a liczba koordynacji.
Poland.
Mioduski, T.
1992.
"Double-double effect and coordination number; Efekt podwojnie-podwojny a liczba koordynacji."
Poland.
@misc{etde_10147459,
title = {Double-double effect and coordination number; Efekt podwojnie-podwojny a liczba koordynacji}
author = {Mioduski, T}
abstractNote = {The original method of interpretation together with its theoretical foundations is developed, making it possible to use location and direction of the double-double (tetrad) effect within the Ln and An series to determine the coordination number (CN) complexes of the f-block elements. The method is applied for potentiometric and radiometric equilibrium studies. It has been pointed and that the decisive factor for the direction of the double-double effect in the case of the Gibbs energy variations is a difference in the CN of the f-element ion between the reaction product complex and that for the reaction substrate the ``regular`` effect for a given tetrad is accompanied by decrease in the CN while the ``reverse`` effect by increase in the CN. (author). 122 refs, 5 tabs, 8 figs.}
place = {Poland}
year = {1992}
month = {Dec}
}
title = {Double-double effect and coordination number; Efekt podwojnie-podwojny a liczba koordynacji}
author = {Mioduski, T}
abstractNote = {The original method of interpretation together with its theoretical foundations is developed, making it possible to use location and direction of the double-double (tetrad) effect within the Ln and An series to determine the coordination number (CN) complexes of the f-block elements. The method is applied for potentiometric and radiometric equilibrium studies. It has been pointed and that the decisive factor for the direction of the double-double effect in the case of the Gibbs energy variations is a difference in the CN of the f-element ion between the reaction product complex and that for the reaction substrate the ``regular`` effect for a given tetrad is accompanied by decrease in the CN while the ``reverse`` effect by increase in the CN. (author). 122 refs, 5 tabs, 8 figs.}
place = {Poland}
year = {1992}
month = {Dec}
}