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Evaluation of performance stability of desulfurization sorbent for coal gas. Characteristics of desulfurization/regeneration repetition under pressurized conditions; Sekitan gas yo datsuryuzai no seino anteisei hyoka. Kaatsu jokenka no datsuryu/saisei kurikaeshi tokusei

Abstract

For commercialization of the fixed bed desulfurization system used for the integrated coal gasification combined cycle power generation, required is long-term stabilization of performance of desulfurizing agent. Since iron oxide based honeycomb desulfurizing agent is used repeatedly in this system, the system conducts removal of sulfur in coal gas (desulfurization), discharge of sulfur in desulfurizing agent (regeneration) and then preparation of desulfurization (reduction). In a test on repeated use of desulfurizing agent carried out under practical operation condition (pressurizing), stabilization of the performance is demonstrated and also a relation between absorbed sulfur and sulfur undischarged by regeneration and reduction (residual sulfur) is examined. Variations of the performance of desulfurizing agent are studied by changes of sulfur compound concentration (breakthrough curves) at the outlet at the time of desulfurizing. Breakthrough curves show almost the same curves on or after 10 cycles of repetition and the performance becomes stabilized. It is found that absorbed sulfur is influenced only by the residual sulfur after the performance is stabilized. 6 refs., 10 figs., 3 tabs.
Authors:
Kobayashi, M; Shirai, Y; Nakayama, T; Tanaka, T [1] 
  1. Central Research Institute of Electric Power Industry, Tokyo (Japan)
Publication Date:
May 01, 1991
Product Type:
Technical Report
Report Number:
CRIE-W-90032
Reference Number:
SCA: 010404; PA: NEDO-91:950808; SN: 92000731929
Resource Relation:
Other Information: PBD: May 1991
Subject:
01 COAL, LIGNITE, AND PEAT; COAL GASIFICATION; COMBINED CYCLES; POWER GENERATION; COAL GAS; DESULFURIZATION; ADDITIVES; PERFORMANCE TESTING; STABILITY; PRESSURIZATION; REGENERATION; IRON OXIDES; HONEYCOMB STRUCTURES; SULFUR COMPOUNDS; 010404; GASIFICATION
OSTI ID:
10142221
Research Organizations:
Central Research Inst. of Electric Power Industry, Tokyo (Japan)
Country of Origin:
Japan
Language:
Japanese
Other Identifying Numbers:
Other: ON: DE92514556; TRN: 91:950808
Availability:
OSTI; NTIS (US Sales Only)
Submitting Site:
NEDO
Size:
21 p.
Announcement Date:
Jul 05, 2005

Citation Formats

Kobayashi, M, Shirai, Y, Nakayama, T, and Tanaka, T. Evaluation of performance stability of desulfurization sorbent for coal gas. Characteristics of desulfurization/regeneration repetition under pressurized conditions; Sekitan gas yo datsuryuzai no seino anteisei hyoka. Kaatsu jokenka no datsuryu/saisei kurikaeshi tokusei. Japan: N. p., 1991. Web.
Kobayashi, M, Shirai, Y, Nakayama, T, & Tanaka, T. Evaluation of performance stability of desulfurization sorbent for coal gas. Characteristics of desulfurization/regeneration repetition under pressurized conditions; Sekitan gas yo datsuryuzai no seino anteisei hyoka. Kaatsu jokenka no datsuryu/saisei kurikaeshi tokusei. Japan.
Kobayashi, M, Shirai, Y, Nakayama, T, and Tanaka, T. 1991. "Evaluation of performance stability of desulfurization sorbent for coal gas. Characteristics of desulfurization/regeneration repetition under pressurized conditions; Sekitan gas yo datsuryuzai no seino anteisei hyoka. Kaatsu jokenka no datsuryu/saisei kurikaeshi tokusei." Japan.
@misc{etde_10142221,
title = {Evaluation of performance stability of desulfurization sorbent for coal gas. Characteristics of desulfurization/regeneration repetition under pressurized conditions; Sekitan gas yo datsuryuzai no seino anteisei hyoka. Kaatsu jokenka no datsuryu/saisei kurikaeshi tokusei}
author = {Kobayashi, M, Shirai, Y, Nakayama, T, and Tanaka, T}
abstractNote = {For commercialization of the fixed bed desulfurization system used for the integrated coal gasification combined cycle power generation, required is long-term stabilization of performance of desulfurizing agent. Since iron oxide based honeycomb desulfurizing agent is used repeatedly in this system, the system conducts removal of sulfur in coal gas (desulfurization), discharge of sulfur in desulfurizing agent (regeneration) and then preparation of desulfurization (reduction). In a test on repeated use of desulfurizing agent carried out under practical operation condition (pressurizing), stabilization of the performance is demonstrated and also a relation between absorbed sulfur and sulfur undischarged by regeneration and reduction (residual sulfur) is examined. Variations of the performance of desulfurizing agent are studied by changes of sulfur compound concentration (breakthrough curves) at the outlet at the time of desulfurizing. Breakthrough curves show almost the same curves on or after 10 cycles of repetition and the performance becomes stabilized. It is found that absorbed sulfur is influenced only by the residual sulfur after the performance is stabilized. 6 refs., 10 figs., 3 tabs.}
place = {Japan}
year = {1991}
month = {May}
}