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Elaboration of y-fanjasite catalysts containing radioactive elements such as uranyl ion in order to obtain aromatic solvents and heavy amines; Elaboration de catalyseurs faujasitiques contenant des cations multivalents dont l`ion uranyle en vue de l`obtention de solvants aromatiques et d`amines lourdes

Abstract

The present work has shown the possibility of ammonia alkylation by n-octanol-l in gaseous phase, in presence of zeolitic catalysts. These catalysts are Y faujasitic types being used in waste water demineralization containing radioactive elements such as uranyl ion. This ion gives to the Y faujasite similar activity and selectivity as those of catalysts containing rare earths or transition metals. Toluene disproportionation has permitted to test beforehand catalysts destined to ammonia alkylation and to compare their mechanism. We have also proved the possibility to produce heavy amines such as tertiary amines which are used as uranium extractant agent. Some zeolites such as ZSM-5, beta, X, A, analcime, HS and Y faujasite type are prepared by hydrothermal synthesis method and characterized by some analysis techniques.
Authors:
Publication Date:
Jun 01, 1990
Product Type:
Thesis/Dissertation
Report Number:
INIS-mf-13151
Reference Number:
SCA: 052001; 400201; PA: AIX-23:037143; SN: 92000726294
Resource Relation:
Other Information: TH: Thesis (Magister Genie Nucleaire).; PBD: Jun 1990
Subject:
12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE WASTES FROM NUCLEAR FACILITIES; 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; RADIOACTIVE WASTE PROCESSING; WASTE PRODUCT UTILIZATION; ZEOLITES; CATALYSTS; ACTINIDES; ALGERIA; AMINATION; RARE EARTHS; URANYL COMPOUNDS; 052001; 400201; WASTE PROCESSING; CHEMICAL AND PHYSICOCHEMICAL PROPERTIES
OSTI ID:
10139851
Research Organizations:
Centre de Developpement des Materiaux, Algiers (Algeria). Lab. d`Analyse
Country of Origin:
Algeria
Language:
French
Other Identifying Numbers:
Other: ON: DE92627041; TRN: DZ9200076037143
Availability:
OSTI; NTIS (US Sales Only); INIS
Submitting Site:
INIS
Size:
183 p.
Announcement Date:
Jul 05, 2005

Citation Formats

Nibou, D. Elaboration of y-fanjasite catalysts containing radioactive elements such as uranyl ion in order to obtain aromatic solvents and heavy amines; Elaboration de catalyseurs faujasitiques contenant des cations multivalents dont l`ion uranyle en vue de l`obtention de solvants aromatiques et d`amines lourdes. Algeria: N. p., 1990. Web.
Nibou, D. Elaboration of y-fanjasite catalysts containing radioactive elements such as uranyl ion in order to obtain aromatic solvents and heavy amines; Elaboration de catalyseurs faujasitiques contenant des cations multivalents dont l`ion uranyle en vue de l`obtention de solvants aromatiques et d`amines lourdes. Algeria.
Nibou, D. 1990. "Elaboration of y-fanjasite catalysts containing radioactive elements such as uranyl ion in order to obtain aromatic solvents and heavy amines; Elaboration de catalyseurs faujasitiques contenant des cations multivalents dont l`ion uranyle en vue de l`obtention de solvants aromatiques et d`amines lourdes." Algeria.
@misc{etde_10139851,
title = {Elaboration of y-fanjasite catalysts containing radioactive elements such as uranyl ion in order to obtain aromatic solvents and heavy amines; Elaboration de catalyseurs faujasitiques contenant des cations multivalents dont l`ion uranyle en vue de l`obtention de solvants aromatiques et d`amines lourdes}
author = {Nibou, D}
abstractNote = {The present work has shown the possibility of ammonia alkylation by n-octanol-l in gaseous phase, in presence of zeolitic catalysts. These catalysts are Y faujasitic types being used in waste water demineralization containing radioactive elements such as uranyl ion. This ion gives to the Y faujasite similar activity and selectivity as those of catalysts containing rare earths or transition metals. Toluene disproportionation has permitted to test beforehand catalysts destined to ammonia alkylation and to compare their mechanism. We have also proved the possibility to produce heavy amines such as tertiary amines which are used as uranium extractant agent. Some zeolites such as ZSM-5, beta, X, A, analcime, HS and Y faujasite type are prepared by hydrothermal synthesis method and characterized by some analysis techniques.}
place = {Algeria}
year = {1990}
month = {Jun}
}