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Measurement of organically bound tritium in urine and feces

Abstract

A bioassay method was developed for directly measuring organically bound tritium (OBT) in urine and feces. Samples first undergo low-temperature distillation and vacuum separation to isolate tritiated water (HTO) and exchangeable tritium. This is followed by converting the non-exchangeable tritium (i.e., OBT) into HTO through oxygen combustion. The method was investigated to: optimise the sample preparation procedures; establish OBT recovery (64% {+-} 7% for urine and 71% {+-} 8% for feces); and, determine the detection limit for OBT in urine (0.3 Bq {center_dot} g{sup -1}) and feces (5 Bq {center_dot} g{sup -1}). The method was evaluated for error sources that are associated with the exchange between HTO and OBT. It is concluded that this bioassay method can reliably measure OBT in urine and feces within the range of {+-} 10%.
Publication Date:
Nov 01, 1993
Product Type:
Technical Report
Report Number:
AECL-10925; COG-93-313.
Reference Number:
SCA: 560161; PA: AIX-25:028021; EDB-94:058284; NTS-94:018299; SN: 94001177634
Resource Relation:
Other Information: PBD: Nov 1993
Subject:
63 RADIATION, THERMAL, AND OTHER ENVIRON. POLLUTANT EFFECTS ON LIVING ORGS. AND BIOL. MAT.; FECES; TRITIUM COMPOUNDS; URINE; ACCURACY; BIOASSAY; SENSITIVITY; TRITIUM; 560161; MAN
OSTI ID:
10138625
Research Organizations:
Atomic Energy of Canada Ltd., Chalk River, ON (Canada). Chalk River Nuclear Labs.
Country of Origin:
Canada
Language:
English
Other Identifying Numbers:
Other: ON: DE94620722; TRN: CA9400214028021
Availability:
OSTI; NTIS (US Sales Only); INIS
Submitting Site:
INIS
Size:
29 p.
Announcement Date:
Jul 05, 2005

Citation Formats

Trivedi, A, Duong, T, Leon, J W, and Linauskas, S H. Measurement of organically bound tritium in urine and feces. Canada: N. p., 1993. Web.
Trivedi, A, Duong, T, Leon, J W, & Linauskas, S H. Measurement of organically bound tritium in urine and feces. Canada.
Trivedi, A, Duong, T, Leon, J W, and Linauskas, S H. 1993. "Measurement of organically bound tritium in urine and feces." Canada.
@misc{etde_10138625,
title = {Measurement of organically bound tritium in urine and feces}
author = {Trivedi, A, Duong, T, Leon, J W, and Linauskas, S H}
abstractNote = {A bioassay method was developed for directly measuring organically bound tritium (OBT) in urine and feces. Samples first undergo low-temperature distillation and vacuum separation to isolate tritiated water (HTO) and exchangeable tritium. This is followed by converting the non-exchangeable tritium (i.e., OBT) into HTO through oxygen combustion. The method was investigated to: optimise the sample preparation procedures; establish OBT recovery (64% {+-} 7% for urine and 71% {+-} 8% for feces); and, determine the detection limit for OBT in urine (0.3 Bq {center_dot} g{sup -1}) and feces (5 Bq {center_dot} g{sup -1}). The method was evaluated for error sources that are associated with the exchange between HTO and OBT. It is concluded that this bioassay method can reliably measure OBT in urine and feces within the range of {+-} 10%.}
place = {Canada}
year = {1993}
month = {Nov}
}