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Determination of alkylphosphates esters by complexation with perchloric acid. Application to the determination of TBP and derivatives in the synthesis mixtures; Dosage des esters du type alkylphosphate par complexation a l`acide perchlorique; Application au dosage du TBP et de ses derives dans les melanges reactionnel de synthese

Abstract

The opportunity to apply the complexation of TBP with perchloric acid to the determination of this ester and its derivatives, i.e. mono- and dibutylphosphoric acids (H2MBP and HDBP) in the synthesis mixtures was investigated. The complexes between the esters and perchloric acids are insoluble in the such complexes seem to be proportional to the concentration of each ester. The effect of the presence of H2MBP and HDBP upon the determination of TBP was also examinated. It was found that small amounts of such derivatives, i.e. smaller than 15%, TBP can be easily determined.
Authors:
Azzouz, A; Boudoukha, Chahrazed; Attou,; Mouloud,; Amedlkouh,; Abdelwahab, [1] 
  1. Centre de Developpement des Materiaux, Algiers (Algeria)
Publication Date:
Oct 01, 1993
Product Type:
Technical Report
Report Number:
CDM/LSO/DSO-57
Reference Number:
SCA: 400201; PA: AIX-25:020938; EDB-94:054842; ERA-19:012671; NTS-94:017802; SN: 94001170851
Resource Relation:
Other Information: PBD: Oct 1993
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; CHEMICAL ANALYSIS; ORGANIC PHOSPHORUS COMPOUNDS; COMPLEXES; PERCHLORIC ACID; 400201; CHEMICAL AND PHYSICOCHEMICAL PROPERTIES
OSTI ID:
10137486
Research Organizations:
Secretariat d`Etat a la Recherche, Algiers (Algeria)
Country of Origin:
Algeria
Language:
French
Other Identifying Numbers:
Other: ON: DE94617432; TRN: DZ9300110020938
Availability:
OSTI; NTIS (US Sales Only); INIS
Submitting Site:
INIS
Size:
17 p.
Announcement Date:
Jul 05, 2005

Citation Formats

Azzouz, A, Boudoukha, Chahrazed, Attou,, Mouloud,, Amedlkouh,, and Abdelwahab,. Determination of alkylphosphates esters by complexation with perchloric acid. Application to the determination of TBP and derivatives in the synthesis mixtures; Dosage des esters du type alkylphosphate par complexation a l`acide perchlorique; Application au dosage du TBP et de ses derives dans les melanges reactionnel de synthese. Algeria: N. p., 1993. Web.
Azzouz, A, Boudoukha, Chahrazed, Attou,, Mouloud,, Amedlkouh,, & Abdelwahab,. Determination of alkylphosphates esters by complexation with perchloric acid. Application to the determination of TBP and derivatives in the synthesis mixtures; Dosage des esters du type alkylphosphate par complexation a l`acide perchlorique; Application au dosage du TBP et de ses derives dans les melanges reactionnel de synthese. Algeria.
Azzouz, A, Boudoukha, Chahrazed, Attou,, Mouloud,, Amedlkouh,, and Abdelwahab,. 1993. "Determination of alkylphosphates esters by complexation with perchloric acid. Application to the determination of TBP and derivatives in the synthesis mixtures; Dosage des esters du type alkylphosphate par complexation a l`acide perchlorique; Application au dosage du TBP et de ses derives dans les melanges reactionnel de synthese." Algeria.
@misc{etde_10137486,
title = {Determination of alkylphosphates esters by complexation with perchloric acid. Application to the determination of TBP and derivatives in the synthesis mixtures; Dosage des esters du type alkylphosphate par complexation a l`acide perchlorique; Application au dosage du TBP et de ses derives dans les melanges reactionnel de synthese}
author = {Azzouz, A, Boudoukha, Chahrazed, Attou,, Mouloud,, Amedlkouh,, and Abdelwahab,}
abstractNote = {The opportunity to apply the complexation of TBP with perchloric acid to the determination of this ester and its derivatives, i.e. mono- and dibutylphosphoric acids (H2MBP and HDBP) in the synthesis mixtures was investigated. The complexes between the esters and perchloric acids are insoluble in the such complexes seem to be proportional to the concentration of each ester. The effect of the presence of H2MBP and HDBP upon the determination of TBP was also examinated. It was found that small amounts of such derivatives, i.e. smaller than 15%, TBP can be easily determined.}
place = {Algeria}
year = {1993}
month = {Oct}
}