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Determination of TBP, HDEHP and TOPO complexed with ferrous thiocyanate by reversed phase liquid chromatography; Dosage chromatographique en phase liquide inversee du TBP, DEHPA et TOPO par intermediaire de leurs complexes avec le thiocyanate de fer

Abstract

The present work deals with the analysis of some organophosphorus extracting agents, e.g. TBP, HDEHP and TOPO by reversed phase liquid chromatography via previous complexation with ferrous thiocyanate. The absorbance wavelengths of the resulting complexes, i.e. TBP:FeSCNK, HDEHP:FeSCNK and TOPO:FeSCNK are respectively 427, 446 and 487nm. Thus, an improvement of such a technique consists in the organophosphorus compounds detection by colorimetry. Subsequently all products and intermediates present in synthesis media can be easily analysed in the same wavelengths range without previous separation or purification.
Authors:
Akliouant, Z; Meddour, L; Azzouz, A [1] 
  1. Centre de Developpement des Materiaux, Algiers (Algeria). Lab. d`Analyse
Publication Date:
Feb 01, 1992
Product Type:
Technical Report
Report Number:
CDM/LSO/DSO-43; MDRTE-CDM-24.
Reference Number:
SCA: 400201; PA: AIX-23:029467; SN: 92000708863
Resource Relation:
Other Information: PBD: Feb 1992
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; HDEHP; EXTRACTION CHROMATOGRAPHY; TBP; THIOCYANATES; TOPO; CHEMISORPTION; 400201; CHEMICAL AND PHYSICOCHEMICAL PROPERTIES
OSTI ID:
10136811
Research Organizations:
Centre de Developpement des Materiaux, Algiers (Algeria). Lab. de Synthese Organique
Country of Origin:
Algeria
Language:
French
Other Identifying Numbers:
Other: ON: DE92622972; TRN: DZ9200074029467
Availability:
OSTI; NTIS (US Sales Only); INIS
Submitting Site:
INIS
Size:
14 p.
Announcement Date:
Jul 05, 2005

Citation Formats

Akliouant, Z, Meddour, L, and Azzouz, A. Determination of TBP, HDEHP and TOPO complexed with ferrous thiocyanate by reversed phase liquid chromatography; Dosage chromatographique en phase liquide inversee du TBP, DEHPA et TOPO par intermediaire de leurs complexes avec le thiocyanate de fer. Algeria: N. p., 1992. Web.
Akliouant, Z, Meddour, L, & Azzouz, A. Determination of TBP, HDEHP and TOPO complexed with ferrous thiocyanate by reversed phase liquid chromatography; Dosage chromatographique en phase liquide inversee du TBP, DEHPA et TOPO par intermediaire de leurs complexes avec le thiocyanate de fer. Algeria.
Akliouant, Z, Meddour, L, and Azzouz, A. 1992. "Determination of TBP, HDEHP and TOPO complexed with ferrous thiocyanate by reversed phase liquid chromatography; Dosage chromatographique en phase liquide inversee du TBP, DEHPA et TOPO par intermediaire de leurs complexes avec le thiocyanate de fer." Algeria.
@misc{etde_10136811,
title = {Determination of TBP, HDEHP and TOPO complexed with ferrous thiocyanate by reversed phase liquid chromatography; Dosage chromatographique en phase liquide inversee du TBP, DEHPA et TOPO par intermediaire de leurs complexes avec le thiocyanate de fer}
author = {Akliouant, Z, Meddour, L, and Azzouz, A}
abstractNote = {The present work deals with the analysis of some organophosphorus extracting agents, e.g. TBP, HDEHP and TOPO by reversed phase liquid chromatography via previous complexation with ferrous thiocyanate. The absorbance wavelengths of the resulting complexes, i.e. TBP:FeSCNK, HDEHP:FeSCNK and TOPO:FeSCNK are respectively 427, 446 and 487nm. Thus, an improvement of such a technique consists in the organophosphorus compounds detection by colorimetry. Subsequently all products and intermediates present in synthesis media can be easily analysed in the same wavelengths range without previous separation or purification.}
place = {Algeria}
year = {1992}
month = {Feb}
}