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Diffusivity and porosity studies in rock matrix. The effect of salinity

Abstract

Diffusion of radionuclides in the pores of rock adjacent to fractures is an important retardation mechanism in the far-field of the repository of nuclear waste. The nature of diffusivity and porosity in rock was studied as a function of various parameters. The phenomena of main interest were dead-end porosity, ion-exclusion and sorption. The rock types studied were rapakivi granite, granite and gneiss, tracer techniques was used as a research method. An analytical solution for outdiffusion from a porous cylinder was developed by applying a corrected form of Fick`s second law for a case where part of the pores are so-called dead-end pores. With this model the theoretical curve could be closely fitted to the measured values. Matrix diffusion was studied in the nature in the island of Haestholmen on the coast of the Gulf of Finland, which due to postglacial land uplift started to rise from the Baltic Sea some 5000 years ago; the land uplift is some 3 mm per year. Rainwater has formed a layer of fresh groundwater floating on top of the saline layer. The coarse- grained granite bedrock of Haestholmen has been investigated for suitability of an underground repository for reactor wastes.
Authors:
Lehikoinen, J; Muurinen, A; Olin, M; Uusheimo, K; Valkiainen, M [1] 
  1. Technical Research Centre of Finland, Espoo (Finland). Reactor Lab.
Publication Date:
Aug 01, 1992
Product Type:
Technical Report
Report Number:
VTT-TIED-1394
Reference Number:
SCA: 540230; 052002; PA: AIX-24:032486; SN: 93000962838
Resource Relation:
Other Information: PBD: Aug 1992
Subject:
54 ENVIRONMENTAL SCIENCES; 12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE WASTES FROM NUCLEAR FACILITIES; DIFFUSION; SALINITY; RADIONUCLIDE MIGRATION; EXPERIMENTAL DATA; FRACTURES; GNEISSES; GRANITES; GROUND WATER; POROUS MATERIALS; RADIOACTIVE WASTE DISPOSAL; UNDERGROUND DISPOSAL; 540230; 052002; RADIOACTIVE MATERIALS MONITORING AND TRANSPORT; WASTE DISPOSAL AND STORAGE
OSTI ID:
10135416
Research Organizations:
Technical Research Centre of Finland, Espoo (Finland)
Country of Origin:
Finland
Language:
English
Other Identifying Numbers:
Other: ON: DE93620715; ISBN 951-38-4208-8; TRN: FI9300010032486
Availability:
OSTI; NTIS; INIS
Submitting Site:
FIN
Size:
[28] p.
Announcement Date:
Jul 05, 2005

Citation Formats

Lehikoinen, J, Muurinen, A, Olin, M, Uusheimo, K, and Valkiainen, M. Diffusivity and porosity studies in rock matrix. The effect of salinity. Finland: N. p., 1992. Web.
Lehikoinen, J, Muurinen, A, Olin, M, Uusheimo, K, & Valkiainen, M. Diffusivity and porosity studies in rock matrix. The effect of salinity. Finland.
Lehikoinen, J, Muurinen, A, Olin, M, Uusheimo, K, and Valkiainen, M. 1992. "Diffusivity and porosity studies in rock matrix. The effect of salinity." Finland.
@misc{etde_10135416,
title = {Diffusivity and porosity studies in rock matrix. The effect of salinity}
author = {Lehikoinen, J, Muurinen, A, Olin, M, Uusheimo, K, and Valkiainen, M}
abstractNote = {Diffusion of radionuclides in the pores of rock adjacent to fractures is an important retardation mechanism in the far-field of the repository of nuclear waste. The nature of diffusivity and porosity in rock was studied as a function of various parameters. The phenomena of main interest were dead-end porosity, ion-exclusion and sorption. The rock types studied were rapakivi granite, granite and gneiss, tracer techniques was used as a research method. An analytical solution for outdiffusion from a porous cylinder was developed by applying a corrected form of Fick`s second law for a case where part of the pores are so-called dead-end pores. With this model the theoretical curve could be closely fitted to the measured values. Matrix diffusion was studied in the nature in the island of Haestholmen on the coast of the Gulf of Finland, which due to postglacial land uplift started to rise from the Baltic Sea some 5000 years ago; the land uplift is some 3 mm per year. Rainwater has formed a layer of fresh groundwater floating on top of the saline layer. The coarse- grained granite bedrock of Haestholmen has been investigated for suitability of an underground repository for reactor wastes.}
place = {Finland}
year = {1992}
month = {Aug}
}