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Sealing properties of cement-based grout materials. Final report on the Rock sealing project

Abstract

This report presents the results of laboratory studies of material properties. A number of different high performance grouts were investigated. The laboratory studies focused on mixtures of sulphate resistant portland cement, silica fume, superplasticizer and water. The ability of the thin films to self seal was confirmed. The surface reactions were studied in specimens of hardened grouts. The leach rates were found to vary with grout and water composition and with temperature. The short-term hydraulic and strength or properties of the hardened grout were determined. These properties were determined for the grouts both in-bulk and as thin-films. The hydraulic conductivities of the bulk, hardened material were found to be less than 10{sup -14} m/s. The hydraulic conductivities of thin films were found to be less than 10{sup -11} m/s. Broken, the hydraulic conductivity of the thin films could be increased to 10{sup -7} m/s. Examination of the leached grout specimens revealed a trend for the pore sizes to decrease with time. The propensity for fractured grouts to self seal was also observed in tests in which the hydraulic conductivity of recompacted mechanically disrupted, granulated grouts was determined. These tests showed that the hydraulic conductivity decreased rapidly with time. The decreases  More>>
Authors:
Onofrei, M; Gray, Malcolm; Shenton, B; Walker, Brad; [1]  Pusch, R; Boergesson, L; Karnland, O [2] 
  1. AECL Research, Whiteshell labs., Pinawa, MB (Canada)
  2. Clay Technology AB, Lund (Sweden)
Publication Date:
Oct 01, 1992
Product Type:
Technical Report
Report Number:
STRIPA-TR-92-28
Reference Number:
SCA: 360603; 052002; PA: AIX-24:032421; SN: 93000962796
Resource Relation:
Other Information: PBD: Oct 1992
Subject:
36 MATERIALS SCIENCE; 12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE WASTES FROM NUCLEAR FACILITIES; SEALING MATERIALS; MATERIALS TESTING; CEMENTS; EXPERIMENTAL DATA; GROUTING; HIGH-LEVEL RADIOACTIVE WASTES; HYDRAULIC CONDUCTIVITY; LEACHING; PERMEABILITY; POROSITY; RADIOACTIVE WASTE DISPOSAL; RHEOLOGY; SURFACE PROPERTIES; TEMPERATURE DEPENDENCE; UNDERGROUND DISPOSAL; 360603; 052002; MECHANICAL PROPERTIES; WASTE DISPOSAL AND STORAGE
OSTI ID:
10135412
Research Organizations:
Swedish Nuclear Fuel and Waste Management Co., Stockholm (Sweden)
Country of Origin:
Sweden
Language:
English
Other Identifying Numbers:
Other: ON: DE93620677; TRN: SE9300040032421
Availability:
OSTI; NTIS; INIS
Submitting Site:
SWDN
Size:
[209] p.
Announcement Date:
Jul 05, 2005

Citation Formats

Onofrei, M, Gray, Malcolm, Shenton, B, Walker, Brad, Pusch, R, Boergesson, L, and Karnland, O. Sealing properties of cement-based grout materials. Final report on the Rock sealing project. Sweden: N. p., 1992. Web.
Onofrei, M, Gray, Malcolm, Shenton, B, Walker, Brad, Pusch, R, Boergesson, L, & Karnland, O. Sealing properties of cement-based grout materials. Final report on the Rock sealing project. Sweden.
Onofrei, M, Gray, Malcolm, Shenton, B, Walker, Brad, Pusch, R, Boergesson, L, and Karnland, O. 1992. "Sealing properties of cement-based grout materials. Final report on the Rock sealing project." Sweden.
@misc{etde_10135412,
title = {Sealing properties of cement-based grout materials. Final report on the Rock sealing project}
author = {Onofrei, M, Gray, Malcolm, Shenton, B, Walker, Brad, Pusch, R, Boergesson, L, and Karnland, O}
abstractNote = {This report presents the results of laboratory studies of material properties. A number of different high performance grouts were investigated. The laboratory studies focused on mixtures of sulphate resistant portland cement, silica fume, superplasticizer and water. The ability of the thin films to self seal was confirmed. The surface reactions were studied in specimens of hardened grouts. The leach rates were found to vary with grout and water composition and with temperature. The short-term hydraulic and strength or properties of the hardened grout were determined. These properties were determined for the grouts both in-bulk and as thin-films. The hydraulic conductivities of the bulk, hardened material were found to be less than 10{sup -14} m/s. The hydraulic conductivities of thin films were found to be less than 10{sup -11} m/s. Broken, the hydraulic conductivity of the thin films could be increased to 10{sup -7} m/s. Examination of the leached grout specimens revealed a trend for the pore sizes to decrease with time. The propensity for fractured grouts to self seal was also observed in tests in which the hydraulic conductivity of recompacted mechanically disrupted, granulated grouts was determined. These tests showed that the hydraulic conductivity decreased rapidly with time. The decreases were associated with decreases in mean pore size. In view of the very low hydraulic conductivity it is likely that surface leaching at the grout/groundwater interface will be that major process by which bulk high-performance grouts may degrade. With the completion of the laboratory, in situ and modelling studies it appears that high-performance cement based grouts can be considered as viable materials for some repository sealing applications. Some of the uncertainties that remain are identified in this report. (54 refs.).}
place = {Sweden}
year = {1992}
month = {Oct}
}