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A study of the fine structure and light transmission in high-density polyethylene sheets from plastic factories in Jordan

Abstract

A study of the morphology and light-transmissivity in nine commercial samples of high-density polyethylene (HDPE) sheets has been carried out. The sheets were produced by the plastic-film extrusion process in nine Jordanian plastic factories. The variations in the samples were determined in terms of crystallinity, crystallite size, heat of fusion, and melting point. X-ray diffraction, ultra violet and visible absorption spectroscopy, and differential scanning calorimetry (DSC) techniques have been used. The nine samples have relatively high x-ray crystallinity (46.1 - 60.8 %). The crystallite size are relatively large (79 - 103 angstroms). The melting point is in the temperature range 127.4 - 132.6 degrees celsius in the samples which were thermally-treated (annealed), and the heat of fusion is in the range (178.6 - 214.0 J/g) in these samples. Annealing of HDPE sheets in vacuum improved the crystallinity especially at temperatures below the melting point (a crystallinity of 73.2% was obtained at 105 degrees celsius). Samples with higher crystallinity showed better transmissivity of visible light. X-ray diffraction crystallinity reveals the variations in the morphology more sensitively than the DSC method. 38 refs., 16 figs., 12 tabs. (A.M.H.).
Authors:
Publication Date:
Dec 31, 1991
Product Type:
Thesis/Dissertation
Report Number:
INIS-mf-13483
Reference Number:
SCA: 665100; PA: AIX-24:031743; SN: 93000956631
Resource Relation:
Other Information: TH: Thesis (M.Sc.).; PBD: 1991
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; POLYETHYLENES; FINE STRUCTURE; LIGHT TRANSMISSION; ABSORPTION SPECTROSCOPY; CALORIMETRY; CRYSTAL STRUCTURE; JORDAN; MORPHOLOGY; ORGANIC COMPOUNDS; ORGANIC POLYMERS; X-RAY DIFFRACTION; 665100; NUCLEAR TECHNIQUES IN CONDENSED MATTER PHYSICS
OSTI ID:
10133789
Research Organizations:
University of Jordan, Amman (Jordan)
Country of Origin:
Jordan
Language:
English
Other Identifying Numbers:
Other: ON: DE93620170; TRN: JO9300009031743
Availability:
OSTI; NTIS (US Sales Only); INIS
Submitting Site:
INIS
Size:
[90] p.
Announcement Date:
Jul 04, 2005

Citation Formats

Dabayneh, K M. A study of the fine structure and light transmission in high-density polyethylene sheets from plastic factories in Jordan. Jordan: N. p., 1991. Web.
Dabayneh, K M. A study of the fine structure and light transmission in high-density polyethylene sheets from plastic factories in Jordan. Jordan.
Dabayneh, K M. 1991. "A study of the fine structure and light transmission in high-density polyethylene sheets from plastic factories in Jordan." Jordan.
@misc{etde_10133789,
title = {A study of the fine structure and light transmission in high-density polyethylene sheets from plastic factories in Jordan}
author = {Dabayneh, K M}
abstractNote = {A study of the morphology and light-transmissivity in nine commercial samples of high-density polyethylene (HDPE) sheets has been carried out. The sheets were produced by the plastic-film extrusion process in nine Jordanian plastic factories. The variations in the samples were determined in terms of crystallinity, crystallite size, heat of fusion, and melting point. X-ray diffraction, ultra violet and visible absorption spectroscopy, and differential scanning calorimetry (DSC) techniques have been used. The nine samples have relatively high x-ray crystallinity (46.1 - 60.8 %). The crystallite size are relatively large (79 - 103 angstroms). The melting point is in the temperature range 127.4 - 132.6 degrees celsius in the samples which were thermally-treated (annealed), and the heat of fusion is in the range (178.6 - 214.0 J/g) in these samples. Annealing of HDPE sheets in vacuum improved the crystallinity especially at temperatures below the melting point (a crystallinity of 73.2% was obtained at 105 degrees celsius). Samples with higher crystallinity showed better transmissivity of visible light. X-ray diffraction crystallinity reveals the variations in the morphology more sensitively than the DSC method. 38 refs., 16 figs., 12 tabs. (A.M.H.).}
place = {Jordan}
year = {1991}
month = {Dec}
}