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Characterization of ashes from wood and straw

Abstract

Three fuels (two bark/wood chips fuels and one straw fuel) and the ashes from the combustion of these fuels in a laboratory fixed bed furnace were studied with regard to element content, crystalline compounds, sintering and melting temperatures. The ashes of the two bark/wood chips fuels contain less potassium and silicon and more calcium than ashes of the straw fuel. The content of potassium is lower than in the original fuel and the content of calcium higher for all fuels. Ashes of the bark/wood chips fuels from substoichiometric experiments showed a higher content of calcium and a lower content of silicon than the ashes from over-stoichiometric experiments. This behaviour could not be seen for the straw ashes. Even though part of the potassium probably leaves the fuel bed as gaseous compounds, there is still enough in the straw ashes to cause sintering problems. The straw ashes melted at about 970 deg C, while the two bark/wood ashes melted at 1465 and 1480 deg C respectively. The combustion temperature was about 1000-1100 deg C for the straw fuel and 1100-1200 deg C for the two bark/wood chips fuels. The main crystalline compounds found were CaCO{sub 3}, CaO, SiO{sub 2}, KCl, K{sub  More>>
Authors:
Olanders, B; Steenari, B M [1] 
  1. Chalmers Univ. of Technology and Gothenburg Univ. (Sweden). Dept. of Inorganic Chemistry
Publication Date:
Jun 01, 1992
Product Type:
Technical Report
Report Number:
NUTEK-FBT-92-15; CTH-OOK-92-03
Reference Number:
SCA: 091000; 098000; PA: SWD-93:007047; SN: 93000949428
Resource Relation:
Other Information: PBD: Jun 1992
Subject:
09 BIOMASS FUELS; ASHES; CHEMICAL ANALYSIS; WOOD FUELS; STRAW; MELTING; COMBUSTION; SINTERING; X-RAY DIFFRACTION; BIOMASS; BARLEY; WHEAT; BARK; TEMPERATURE RANGE 1000-4000 K; BENCH-SCALE EXPERIMENTS; EXPERIMENTAL DATA; 091000; 098000; PROPERTIES AND COMPOSITION; WASTE MANAGEMENT
OSTI ID:
10132715
Research Organizations:
Swedish National Board for Industrial and Technical Development (NUTEK), Stockholm (Sweden); Chalmers Univ. of Technology and Univ. of Goeteborg, Goeteborg (Sweden). Dept. of Inorganic Chemistry
Country of Origin:
Sweden
Language:
English
Other Identifying Numbers:
Other: ON: DE93769982; CNN: Project NUTEK-276-508; TRN: SE9307047
Availability:
OSTI; NTIS
Submitting Site:
SWD
Size:
39 p.
Announcement Date:
Jul 04, 2005

Citation Formats

Olanders, B, and Steenari, B M. Characterization of ashes from wood and straw. Sweden: N. p., 1992. Web.
Olanders, B, & Steenari, B M. Characterization of ashes from wood and straw. Sweden.
Olanders, B, and Steenari, B M. 1992. "Characterization of ashes from wood and straw." Sweden.
@misc{etde_10132715,
title = {Characterization of ashes from wood and straw}
author = {Olanders, B, and Steenari, B M}
abstractNote = {Three fuels (two bark/wood chips fuels and one straw fuel) and the ashes from the combustion of these fuels in a laboratory fixed bed furnace were studied with regard to element content, crystalline compounds, sintering and melting temperatures. The ashes of the two bark/wood chips fuels contain less potassium and silicon and more calcium than ashes of the straw fuel. The content of potassium is lower than in the original fuel and the content of calcium higher for all fuels. Ashes of the bark/wood chips fuels from substoichiometric experiments showed a higher content of calcium and a lower content of silicon than the ashes from over-stoichiometric experiments. This behaviour could not be seen for the straw ashes. Even though part of the potassium probably leaves the fuel bed as gaseous compounds, there is still enough in the straw ashes to cause sintering problems. The straw ashes melted at about 970 deg C, while the two bark/wood ashes melted at 1465 and 1480 deg C respectively. The combustion temperature was about 1000-1100 deg C for the straw fuel and 1100-1200 deg C for the two bark/wood chips fuels. The main crystalline compounds found were CaCO{sub 3}, CaO, SiO{sub 2}, KCl, K{sub 2}SO{sub 4} and MgO. KCl and K{sub 2}SO{sub 4} was clearly found in the ashes from straw but only traces in the ashes from the bark/wood chips fuels. CaCO{sub 3} was present in ashes prepared at 400 deg C and was converted to CaO when the ashes were heated above that temperature. Also calcium silicates, potassium calcium silicate and calcium magnesium silicate were found. All potassium containing compounds detected have low melting temperatures, which can be an explanation for the sintering tendency of the straw ashes. The crystalline compounds found in the ashes are examples of the compounds which can form during the combustion of biomass fuels and also, possibly act as catalytic substance for NO reduction. (authors) (15 refs., 7 figs., 9 tabs.).}
place = {Sweden}
year = {1992}
month = {Jun}
}