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Solubility of the redox-sensitive radionuclides {sup 99}Tc and {sup 237}Np under reducing conditions in neutral to alkaline solutions. Effect of carbonate

Abstract

We have studied the solubility of Tc(4) and Np(4) hydrous oxides in aqueous solution as a function of pH and carbonate concentration. The solid phases used were prepared by electro-reduction and precipitation on platinum electrodes. The implications on the speciation and mobility of Tc(4) and Np(4) in groundwater, as well as those of U(4) and Pu(4), are discussed.
Authors:
Eriksen, T E; Ndalamba, P; Cui, D; [1]  Bruno, J; Caceci, M; Spahiu, K [2] 
  1. Royal Inst. of Tech., Stockholm (Sweden). Dept. of Nuclear Chemistry
  2. MBT Technologia Ambiental, Cerdanyola (Spain)
Publication Date:
Sep 01, 1993
Product Type:
Technical Report
Report Number:
SKB-TR-93-18
Reference Number:
SCA: 052002; 400201; PA: AIX-25:019216; EDB-94:034596; ERA-19:011760; NTS-94:014996; SN: 94001160024
Resource Relation:
Other Information: PBD: Sep 1993
Subject:
12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE WASTES FROM NUCLEAR FACILITIES; 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; CHEMICAL REACTIONS; EQUILIBRIUM; NEPTUNIUM; SOLUBILITY; TECHNETIUM; AQUEOUS SOLUTIONS; CARBONATES; EXPERIMENTAL DATA; GROUND WATER; OXIDATION; RADIOACTIVE WASTE DISPOSAL; RADIONUCLIDE MIGRATION; REDUCTION; ROCK-FLUID INTERACTIONS; UNDERGROUND DISPOSAL; 052002; 400201; WASTE DISPOSAL AND STORAGE; CHEMICAL AND PHYSICOCHEMICAL PROPERTIES
OSTI ID:
10130629
Research Organizations:
Swedish Nuclear Fuel and Waste Management Co., Stockholm (Sweden)
Country of Origin:
Sweden
Language:
English
Other Identifying Numbers:
Journal ID: ISSN 0284-3757; Other: ON: DE94616530; TRN: SE9300342019216
Availability:
OSTI; NTIS; INIS
Submitting Site:
SWDN
Size:
40 p.
Announcement Date:
Jul 04, 2005

Citation Formats

Eriksen, T E, Ndalamba, P, Cui, D, Bruno, J, Caceci, M, and Spahiu, K. Solubility of the redox-sensitive radionuclides {sup 99}Tc and {sup 237}Np under reducing conditions in neutral to alkaline solutions. Effect of carbonate. Sweden: N. p., 1993. Web.
Eriksen, T E, Ndalamba, P, Cui, D, Bruno, J, Caceci, M, & Spahiu, K. Solubility of the redox-sensitive radionuclides {sup 99}Tc and {sup 237}Np under reducing conditions in neutral to alkaline solutions. Effect of carbonate. Sweden.
Eriksen, T E, Ndalamba, P, Cui, D, Bruno, J, Caceci, M, and Spahiu, K. 1993. "Solubility of the redox-sensitive radionuclides {sup 99}Tc and {sup 237}Np under reducing conditions in neutral to alkaline solutions. Effect of carbonate." Sweden.
@misc{etde_10130629,
title = {Solubility of the redox-sensitive radionuclides {sup 99}Tc and {sup 237}Np under reducing conditions in neutral to alkaline solutions. Effect of carbonate}
author = {Eriksen, T E, Ndalamba, P, Cui, D, Bruno, J, Caceci, M, and Spahiu, K}
abstractNote = {We have studied the solubility of Tc(4) and Np(4) hydrous oxides in aqueous solution as a function of pH and carbonate concentration. The solid phases used were prepared by electro-reduction and precipitation on platinum electrodes. The implications on the speciation and mobility of Tc(4) and Np(4) in groundwater, as well as those of U(4) and Pu(4), are discussed.}
place = {Sweden}
year = {1993}
month = {Sep}
}