Abstract
The N,N`-dimethyl N,N`-dibutyl tetradecylmalonamide (DMDBTDMA) with an aliphatic diluent can extract trivalent actinides from nitric solutions. Then it is useful to know extraction equilibria of nitric acid with these molecules. They are determined from partition coefficients in function of acidity and amide concentration, and determination of water in the organic phase. Aggregates of diamide molecules are formed in non-acid solutions. Structures of complexes are determined by infrared spectroscopy. The same study is carried out for perchloric acid.
Citation Formats
Nigond, L, Musikas, C, and Cuillerdier, C.
Extraction of nitric acid and perchloric acid with N,N,N`,N`-tetraalkyl 2-alkyl propane 1,3-diamides; Extractions des acides: HNO{sub 3} et HClO{sub 4} par les N,N,N`,N`-tetraalkyl-alkyl-2 propane diamides-1,3.
France: N. p.,
1992.
Web.
Nigond, L, Musikas, C, & Cuillerdier, C.
Extraction of nitric acid and perchloric acid with N,N,N`,N`-tetraalkyl 2-alkyl propane 1,3-diamides; Extractions des acides: HNO{sub 3} et HClO{sub 4} par les N,N,N`,N`-tetraalkyl-alkyl-2 propane diamides-1,3.
France.
Nigond, L, Musikas, C, and Cuillerdier, C.
1992.
"Extraction of nitric acid and perchloric acid with N,N,N`,N`-tetraalkyl 2-alkyl propane 1,3-diamides; Extractions des acides: HNO{sub 3} et HClO{sub 4} par les N,N,N`,N`-tetraalkyl-alkyl-2 propane diamides-1,3."
France.
@misc{etde_10123435,
title = {Extraction of nitric acid and perchloric acid with N,N,N`,N`-tetraalkyl 2-alkyl propane 1,3-diamides; Extractions des acides: HNO{sub 3} et HClO{sub 4} par les N,N,N`,N`-tetraalkyl-alkyl-2 propane diamides-1,3}
author = {Nigond, L, Musikas, C, and Cuillerdier, C}
abstractNote = {The N,N`-dimethyl N,N`-dibutyl tetradecylmalonamide (DMDBTDMA) with an aliphatic diluent can extract trivalent actinides from nitric solutions. Then it is useful to know extraction equilibria of nitric acid with these molecules. They are determined from partition coefficients in function of acidity and amide concentration, and determination of water in the organic phase. Aggregates of diamide molecules are formed in non-acid solutions. Structures of complexes are determined by infrared spectroscopy. The same study is carried out for perchloric acid.}
place = {France}
year = {1992}
month = {Dec}
}
title = {Extraction of nitric acid and perchloric acid with N,N,N`,N`-tetraalkyl 2-alkyl propane 1,3-diamides; Extractions des acides: HNO{sub 3} et HClO{sub 4} par les N,N,N`,N`-tetraalkyl-alkyl-2 propane diamides-1,3}
author = {Nigond, L, Musikas, C, and Cuillerdier, C}
abstractNote = {The N,N`-dimethyl N,N`-dibutyl tetradecylmalonamide (DMDBTDMA) with an aliphatic diluent can extract trivalent actinides from nitric solutions. Then it is useful to know extraction equilibria of nitric acid with these molecules. They are determined from partition coefficients in function of acidity and amide concentration, and determination of water in the organic phase. Aggregates of diamide molecules are formed in non-acid solutions. Structures of complexes are determined by infrared spectroscopy. The same study is carried out for perchloric acid.}
place = {France}
year = {1992}
month = {Dec}
}