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Crystallization of Al-based metallic glasses: Structural aspects

Abstract

Crystallization reactions, crystal morphologies and evolutions have been studied in meltspun binary Al-Y and ternary Al-Fe-Y metallic glasses using X-ray diffraction, differential scanning calorimetry, electron microscopy and Moessbauer spectroscopy. The binary samples crystallize in an one-stage or two-stage primary reaction of {alpha} Al phase, followed by polymorphous reactions of different metastable compounds. The ternary glasses devitrify in either polymorphous or eutectic reactions. The ternary crystalline compounds are characteristically a metastable Al{sub 9} (Fe,Y){sub 2} phase with strongly textured columnar morphology, and a tetragonal Al{sub 70}Fe{sub 16}Y{sub 14} phase. The structure of the early stage crystallization products depends on the nature of the short range chemical order structures existing at different temperatures in the melts, which are partly retained in the glass phases. (orig.).
Publication Date:
Dec 31, 1991
Product Type:
Technical Report
Report Number:
KU-HCOE-FL2-R-91-17
Reference Number:
SCA: 360102; PA: AIX-23:018597; SN: 92000664422
Resource Relation:
Other Information: PBD: 1991
Subject:
36 MATERIALS SCIENCE; ALUMINIUM BASE ALLOYS; CRYSTALLIZATION; BINARY ALLOY SYSTEMS; CRYSTAL STRUCTURE; ELECTRON MICROSCOPY; METALLIC GLASSES; MOESSBAUER EFFECT; TERNARY ALLOY SYSTEMS; X-RAY DIFFRACTION; YTTRIUM ALLOYS; 360102; STRUCTURE AND PHASE STUDIES
OSTI ID:
10120607
Research Organizations:
Copenhagen Univ. (Denmark). H.C. Oersted Inst.
Country of Origin:
Denmark
Language:
English
Other Identifying Numbers:
Other: ON: DE92617639; TRN: DK92C0004018597
Availability:
OSTI; NTIS (US Sales Only); INIS
Submitting Site:
DKN
Size:
40 p.
Announcement Date:
Jun 30, 2005

Citation Formats

Li, Q, Johnson, E, Madsen, M B, Johansen, A, and Sarholt-Kristensen, L. Crystallization of Al-based metallic glasses: Structural aspects. Denmark: N. p., 1991. Web.
Li, Q, Johnson, E, Madsen, M B, Johansen, A, & Sarholt-Kristensen, L. Crystallization of Al-based metallic glasses: Structural aspects. Denmark.
Li, Q, Johnson, E, Madsen, M B, Johansen, A, and Sarholt-Kristensen, L. 1991. "Crystallization of Al-based metallic glasses: Structural aspects." Denmark.
@misc{etde_10120607,
title = {Crystallization of Al-based metallic glasses: Structural aspects}
author = {Li, Q, Johnson, E, Madsen, M B, Johansen, A, and Sarholt-Kristensen, L}
abstractNote = {Crystallization reactions, crystal morphologies and evolutions have been studied in meltspun binary Al-Y and ternary Al-Fe-Y metallic glasses using X-ray diffraction, differential scanning calorimetry, electron microscopy and Moessbauer spectroscopy. The binary samples crystallize in an one-stage or two-stage primary reaction of {alpha} Al phase, followed by polymorphous reactions of different metastable compounds. The ternary glasses devitrify in either polymorphous or eutectic reactions. The ternary crystalline compounds are characteristically a metastable Al{sub 9} (Fe,Y){sub 2} phase with strongly textured columnar morphology, and a tetragonal Al{sub 70}Fe{sub 16}Y{sub 14} phase. The structure of the early stage crystallization products depends on the nature of the short range chemical order structures existing at different temperatures in the melts, which are partly retained in the glass phases. (orig.).}
place = {Denmark}
year = {1991}
month = {Dec}
}