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A study of vibrational relaxation of electronically-excited molecules

Abstract

The time kinetics of the vibrational relaxation of excimers is studied in the diffusional approximation. Simple formulae for functions of nonstationary vibrational distribution are found for the electronically excited molecules. Some spectral-kinetic dependencies of the excimer luminescence are explained in a new way. The possibilities of the determination of excimer parameters are discussed. The dependence of energetical characteristics of excimer lasers on these parameters is particularly emphasized. (author). 22 refs, 5 figs.
Authors:
Datsyuk, V V; [1]  Izmailov, I A; [2]  Kochelap, V A
  1. T. Shevchenko Univ., Kiev (Ukraine). Lab. of Theoretical Physics
  2. Academy of Sciences of Ukraine, Kiev (Ukraine). Inst. of Semiconductors
Publication Date:
Sep 01, 1992
Product Type:
Technical Report
Report Number:
IC-92/261
Reference Number:
SCA: 664200; 664100; PA: AIX-24:009151; SN: 93000933555
Resource Relation:
Other Information: PBD: Sep 1992
Subject:
74 ATOMIC AND MOLECULAR PHYSICS; EXCIMER LASERS; VIBRATIONAL STATES; ANALYTICAL SOLUTION; FOKKER-PLANCK EQUATION; LUMINESCENCE; RELAXATION; 664200; 664100; SPECTRA OF ATOMS AND MOLECULES AND THEIR INTERACTIONS WITH PHOTONS; THEORY OF ELECTRONIC STRUCTURE OF ATOMS AND MOLECULES
OSTI ID:
10119809
Research Organizations:
International Centre for Theoretical Physics (ICTP), Trieste (Italy)
Country of Origin:
IAEA
Language:
English
Other Identifying Numbers:
Other: ON: DE93613553; TRN: XA9233073009151
Availability:
OSTI; NTIS (US Sales Only); INIS
Submitting Site:
INIS
Size:
[26] p.
Announcement Date:
Jun 30, 2005

Citation Formats

Datsyuk, V V, Izmailov, I A, and Kochelap, V A. A study of vibrational relaxation of electronically-excited molecules. IAEA: N. p., 1992. Web.
Datsyuk, V V, Izmailov, I A, & Kochelap, V A. A study of vibrational relaxation of electronically-excited molecules. IAEA.
Datsyuk, V V, Izmailov, I A, and Kochelap, V A. 1992. "A study of vibrational relaxation of electronically-excited molecules." IAEA.
@misc{etde_10119809,
title = {A study of vibrational relaxation of electronically-excited molecules}
author = {Datsyuk, V V, Izmailov, I A, and Kochelap, V A}
abstractNote = {The time kinetics of the vibrational relaxation of excimers is studied in the diffusional approximation. Simple formulae for functions of nonstationary vibrational distribution are found for the electronically excited molecules. Some spectral-kinetic dependencies of the excimer luminescence are explained in a new way. The possibilities of the determination of excimer parameters are discussed. The dependence of energetical characteristics of excimer lasers on these parameters is particularly emphasized. (author). 22 refs, 5 figs.}
place = {IAEA}
year = {1992}
month = {Sep}
}