Abstract
Melting parameters and transport coefficients in the melt are collated for halides of monovalent, divalent and trivalent metals. A number of systems show a deficit of entropy of melting relative to the linear relationships between entropy change and relative volume change on melting that are found to be approximately obeyed by a majority of halides. These behaviours are discussed on the basis of structural and transport data. The deviating systems are classified into three main classes, namely (i) fast-ion conductors in the high-temperature crystal phase such as AgI, (ii) strongly structured network-like systems such as ZnCl{sub 2}, and (iii) molecular systems melting into associated molecular liquids such as SbCl{sub 3}. (author). 35 refs, 1 fig., 3 tabs.
Citation Formats
Akdeniz, Z, and Tosi, M P.
Correlations between entropy and volume of melting in halide salts.
IAEA: N. p.,
1991.
Web.
Akdeniz, Z, & Tosi, M P.
Correlations between entropy and volume of melting in halide salts.
IAEA.
Akdeniz, Z, and Tosi, M P.
1991.
"Correlations between entropy and volume of melting in halide salts."
IAEA.
@misc{etde_10118558,
title = {Correlations between entropy and volume of melting in halide salts}
author = {Akdeniz, Z, and Tosi, M P}
abstractNote = {Melting parameters and transport coefficients in the melt are collated for halides of monovalent, divalent and trivalent metals. A number of systems show a deficit of entropy of melting relative to the linear relationships between entropy change and relative volume change on melting that are found to be approximately obeyed by a majority of halides. These behaviours are discussed on the basis of structural and transport data. The deviating systems are classified into three main classes, namely (i) fast-ion conductors in the high-temperature crystal phase such as AgI, (ii) strongly structured network-like systems such as ZnCl{sub 2}, and (iii) molecular systems melting into associated molecular liquids such as SbCl{sub 3}. (author). 35 refs, 1 fig., 3 tabs.}
place = {IAEA}
year = {1991}
month = {Sep}
}
title = {Correlations between entropy and volume of melting in halide salts}
author = {Akdeniz, Z, and Tosi, M P}
abstractNote = {Melting parameters and transport coefficients in the melt are collated for halides of monovalent, divalent and trivalent metals. A number of systems show a deficit of entropy of melting relative to the linear relationships between entropy change and relative volume change on melting that are found to be approximately obeyed by a majority of halides. These behaviours are discussed on the basis of structural and transport data. The deviating systems are classified into three main classes, namely (i) fast-ion conductors in the high-temperature crystal phase such as AgI, (ii) strongly structured network-like systems such as ZnCl{sub 2}, and (iii) molecular systems melting into associated molecular liquids such as SbCl{sub 3}. (author). 35 refs, 1 fig., 3 tabs.}
place = {IAEA}
year = {1991}
month = {Sep}
}