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Studies on the preparation of labelled compounds for {gamma}-scintigraphy use

Abstract

To develop {sup 99m}Tc instant labelling kit of d,1-HMPAO and {sup 131}I labelled IMP for the regional cerebral blood flow scintigraphic use, d,1-HMPAO and IMP were synthesized. The former was prepared from 2,3-butadione monoxim and 2,2-dimethyl-1,3-propanediamine in the presence of cation exchange resin, and then selective reduction of imine bond with sodium borohydride followed by fractional crystallization of diastereometric mixture of HMPAO. The latter was prepared by condensation of p-iodophenylpropanone with isopropylamine, and then reduction of double bond with sodium borohydride. For the preparation of {sup 99m}Tc labelled HSA, experiments on incorporation of bifunctional chelating agent of DTPA to HSA, establishment of optimal conditions of {sup 99m}Tc labelling, determination of labelling yield and radiochemical purity, and examination of stability were carried out. (Author).
Authors:
Kim, Jae Rok; Park, Kyung Bae; Awh, Ok Doo [1] 
  1. Korea Atomic Energy Research Inst., Daeduk (Korea, Republic of)
Publication Date:
Mar 01, 1991
Product Type:
Technical Report
Report Number:
KAERI/RR-990/90
Reference Number:
SCA: 550601; 400703; PA: AIX-23:017016; SN: 92000661026
Resource Relation:
Other Information: PBD: Mar 1991
Subject:
62 RADIOLOGY AND NUCLEAR MEDICINE; 38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY; LABELLED COMPOUNDS; CHEMICAL PREPARATION; SCINTISCANNING; ALBUMINS; OXIMES; RABBITS; RADIOMETRIC ANALYSIS; TECHNETIUM 99; 550601; 400703; UNSEALED RADIONUCLIDES IN DIAGNOSTICS; RADIOISOTOPE PRODUCTION
OSTI ID:
10117479
Research Organizations:
Korea Atomic Energy Research Inst., Daeduk (Korea, Republic of)
Country of Origin:
Korea, Republic of
Language:
Korean
Other Identifying Numbers:
Other: ON: DE92616541; TRN: KR9100136017016
Availability:
OSTI; NTIS (US Sales Only); INIS
Submitting Site:
INIS
Size:
61 p.
Announcement Date:
Jun 30, 2005

Citation Formats

Kim, Jae Rok, Park, Kyung Bae, and Awh, Ok Doo. Studies on the preparation of labelled compounds for {gamma}-scintigraphy use. Korea, Republic of: N. p., 1991. Web.
Kim, Jae Rok, Park, Kyung Bae, & Awh, Ok Doo. Studies on the preparation of labelled compounds for {gamma}-scintigraphy use. Korea, Republic of.
Kim, Jae Rok, Park, Kyung Bae, and Awh, Ok Doo. 1991. "Studies on the preparation of labelled compounds for {gamma}-scintigraphy use." Korea, Republic of.
@misc{etde_10117479,
title = {Studies on the preparation of labelled compounds for {gamma}-scintigraphy use}
author = {Kim, Jae Rok, Park, Kyung Bae, and Awh, Ok Doo}
abstractNote = {To develop {sup 99m}Tc instant labelling kit of d,1-HMPAO and {sup 131}I labelled IMP for the regional cerebral blood flow scintigraphic use, d,1-HMPAO and IMP were synthesized. The former was prepared from 2,3-butadione monoxim and 2,2-dimethyl-1,3-propanediamine in the presence of cation exchange resin, and then selective reduction of imine bond with sodium borohydride followed by fractional crystallization of diastereometric mixture of HMPAO. The latter was prepared by condensation of p-iodophenylpropanone with isopropylamine, and then reduction of double bond with sodium borohydride. For the preparation of {sup 99m}Tc labelled HSA, experiments on incorporation of bifunctional chelating agent of DTPA to HSA, establishment of optimal conditions of {sup 99m}Tc labelling, determination of labelling yield and radiochemical purity, and examination of stability were carried out. (Author).}
place = {Korea, Republic of}
year = {1991}
month = {Mar}
}