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Multi-stage grafting and simultaneous co-grafting of acrylic acid and vinyl pyrrolidone onto polyethylene induced by {gamma}-ray irradiation

Technical Report:

Abstract

Studies on multi-stage grafting or simultaneous co-grafting of acrylic acid and vinyl pyrrolidone onto polyethylene have been carried out in an attempt to introduce different functional groups into polymers in some ordered states. In the multi-stage grafting, time conversion curves of grafting and graft percent of the second stage depend on the order of monomer to be grafted, and on graft percent of the first-stage grafting. In simultaneous co-grafting, time conversion curves of grafting reaction and graft percent of each monomer depend on monomer ratio in the solution. Effect of graft percent on electric resistance across the grafted film was also found to depend on the mode of multi-stage grafting or simultaneous co-grafting. Results of some trial experiments to establish the grafting conditions are also described. (author).
Authors:
Qin, Gen-Min; Kaji, Kanako; Hatada, Motoyoshi [1] 
  1. Japan Atomic Energy Research Inst., Neyagawa, Osaka (Japan). Osaka Lab. for Radiation Chemistry
Publication Date:
Jul 01, 1991
Product Type:
Technical Report
Report Number:
JAERI-M-91-106
Reference Number:
SCA: 400600; PA: JPN-91:012010; SN: 92000659044
Resource Relation:
Other Information: PBD: Jul 1991
Subject:
38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY; POLYETHYLENES; GRAFT POLYMERS; ACRYLIC ACID; PYRROLIDONES; CHEMICAL RADIATION EFFECTS; POLYMERIZATION; GAMMA RADIATION; IRRADIATION; CHEMICAL REACTION KINETICS; ELECTRIC CONDUCTIVITY; 400600; RADIATION CHEMISTRY
OSTI ID:
10116982
Research Organizations:
Japan Atomic Energy Research Inst., Tokyo (Japan)
Country of Origin:
Japan
Language:
English
Other Identifying Numbers:
Other: ON: DE92767932; TRN: JP9112010
Availability:
OSTI; NTIS (US Sales Only); INIS
Submitting Site:
JPN
Size:
119 p.
Announcement Date:
Jun 30, 2005

Technical Report:

Citation Formats

Qin, Gen-Min, Kaji, Kanako, and Hatada, Motoyoshi. Multi-stage grafting and simultaneous co-grafting of acrylic acid and vinyl pyrrolidone onto polyethylene induced by {gamma}-ray irradiation. Japan: N. p., 1991. Web.
Qin, Gen-Min, Kaji, Kanako, & Hatada, Motoyoshi. Multi-stage grafting and simultaneous co-grafting of acrylic acid and vinyl pyrrolidone onto polyethylene induced by {gamma}-ray irradiation. Japan.
Qin, Gen-Min, Kaji, Kanako, and Hatada, Motoyoshi. 1991. "Multi-stage grafting and simultaneous co-grafting of acrylic acid and vinyl pyrrolidone onto polyethylene induced by {gamma}-ray irradiation." Japan.
@misc{etde_10116982,
title = {Multi-stage grafting and simultaneous co-grafting of acrylic acid and vinyl pyrrolidone onto polyethylene induced by {gamma}-ray irradiation}
author = {Qin, Gen-Min, Kaji, Kanako, and Hatada, Motoyoshi}
abstractNote = {Studies on multi-stage grafting or simultaneous co-grafting of acrylic acid and vinyl pyrrolidone onto polyethylene have been carried out in an attempt to introduce different functional groups into polymers in some ordered states. In the multi-stage grafting, time conversion curves of grafting and graft percent of the second stage depend on the order of monomer to be grafted, and on graft percent of the first-stage grafting. In simultaneous co-grafting, time conversion curves of grafting reaction and graft percent of each monomer depend on monomer ratio in the solution. Effect of graft percent on electric resistance across the grafted film was also found to depend on the mode of multi-stage grafting or simultaneous co-grafting. Results of some trial experiments to establish the grafting conditions are also described. (author).}
place = {Japan}
year = {1991}
month = {Jul}
}