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ICP-MS as advantageous analytical technique for the determination of long-lived /sup 99/Tc in the environment

Abstract

Technetium (Tc) was the first artificially created by man and has no stable isotope. The most crucial technetium isotope environmentally /sup 99/Tc is a pure beta emitter with a half-life of 2.1 X 105 years. The main source of /sup 99/Tc to the environment is the disposal of liquid wastes from nuclear installations or during separation and recovery of spent nuclear fuels. Because of its long half life, high fission yield, mobility and current interest in the collective long term doses, it is necessary to establish a knowledge of the behavior of /sup 99/Tc in the environment for complete assessment of the impact of nuclear industry. Due to various analytical difficulties however, data on the behavior of Tc in the environment are limited. In the literature, many techniques are reported for the analysis of Tc. A very sensitive, precise and powerful technique is required which can be applied to environmental samples in order to gain information by obtaining more precise data to assess the impact of Tc releases on man. Attention has been focussed for this purpose on a new powerful technique i.e. inductively coupled plasma mass spectrometry (ICP-MS). This report has been directed towards the development of ICP-MS. The  More>>
Authors:
Ihsanullah, [1] 
  1. Pakistan Inst. of Nuclear Science and Technology, Islamabad (Pakistan). Health Physics Div.
Publication Date:
May 01, 1992
Product Type:
Technical Report
Report Number:
PINSTECH-HPD-142
Reference Number:
SCA: 400102; PA: AIX-26:014171; EDB-95:030009; SN: 95001328175
Resource Relation:
Other Information: PBD: May 1992
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; TECHNETIUM 99; ENVIRONMENTAL IMPACTS; MASS SPECTROSCOPY; ELEMENT ABUNDANCE; NUCLEAR INDUSTRY; SAMPLE PREPARATION; 400102; CHEMICAL AND SPECTRAL PROCEDURES
OSTI ID:
10114002
Research Organizations:
Pakistan Inst. of Nuclear Science and Technology, Islamabad (Pakistan). Health Physics Div.
Country of Origin:
Pakistan
Language:
English
Other Identifying Numbers:
Other: ON: DE95614628; TRN: PK9400133014171
Availability:
OSTI; NTIS (US Sales Only); INIS
Submitting Site:
INIS
Size:
14 p.
Announcement Date:
Jun 30, 2005

Citation Formats

Ihsanullah,. ICP-MS as advantageous analytical technique for the determination of long-lived /sup 99/Tc in the environment. Pakistan: N. p., 1992. Web.
Ihsanullah,. ICP-MS as advantageous analytical technique for the determination of long-lived /sup 99/Tc in the environment. Pakistan.
Ihsanullah,. 1992. "ICP-MS as advantageous analytical technique for the determination of long-lived /sup 99/Tc in the environment." Pakistan.
@misc{etde_10114002,
title = {ICP-MS as advantageous analytical technique for the determination of long-lived /sup 99/Tc in the environment}
author = {Ihsanullah,}
abstractNote = {Technetium (Tc) was the first artificially created by man and has no stable isotope. The most crucial technetium isotope environmentally /sup 99/Tc is a pure beta emitter with a half-life of 2.1 X 105 years. The main source of /sup 99/Tc to the environment is the disposal of liquid wastes from nuclear installations or during separation and recovery of spent nuclear fuels. Because of its long half life, high fission yield, mobility and current interest in the collective long term doses, it is necessary to establish a knowledge of the behavior of /sup 99/Tc in the environment for complete assessment of the impact of nuclear industry. Due to various analytical difficulties however, data on the behavior of Tc in the environment are limited. In the literature, many techniques are reported for the analysis of Tc. A very sensitive, precise and powerful technique is required which can be applied to environmental samples in order to gain information by obtaining more precise data to assess the impact of Tc releases on man. Attention has been focussed for this purpose on a new powerful technique i.e. inductively coupled plasma mass spectrometry (ICP-MS). This report has been directed towards the development of ICP-MS. The technique gives a very high sensitivity enabling long lived radionuclides including /sup 99/Tc to be measured directly down to pg ml-1 levels in solution. Because of its versatility ICP-MS is finding applications for trace multielement analysis and low detection limits in almost all fields. (author).}
place = {Pakistan}
year = {1992}
month = {May}
}