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Standardization of /sup 13/CO/sub 2/ production procedure from organic matter for mass spectrometric analysis

Abstract

This report summarizes the ways and means by which /sup 13/Co/sub 2/ production procedure from organic matter can be standardized. Optimum sample preparation conditions were determined to get reproducible results. Plant combustion for six minutes at 900-1000 degree C with pure O/sub 2/ and ten minutes for conversion of CO to CO/ sub 2/ over CUO gauze at 850 degree C have been found optimum conditions. Internal standards: PINSTECH wheat straw, PINSTECH grass sample, Glucose-D glaxo PINSTECH and polyethylene foil PINSTECH were selected, and calibrated against IAEA Sucrose and polyethylene foil standards. These internal standards have been used for correction of delta 13 C results. The mechanisms for the correction of results has been described. Causes of isotope fractionation of plant samples were determined. Statistical summary of measured results for delta /sup 13/C standards has also been given. (author).
Authors:
Sajjad, M I; Latif, Z; Tasneem, M A; Ali, M; Bilal, R [1] 
  1. Pakistan Inst. of Nuclear Science and Technology, Islamabad (Pakistan). Radiation and Isotope Application Div.
Publication Date:
Nov 01, 1993
Product Type:
Technical Report
Report Number:
PINSTECH-RIAD-138
Reference Number:
SCA: 400102; PA: AIX-26:014172; EDB-95:029999; SN: 95001328176
Resource Relation:
Other Information: PBD: Nov 1993
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; CARBON DIOXIDE; MASS SPECTROSCOPY; CALIBRATION STANDARDS; CARBON 13; GLUCOSE; SAMPLE PREPARATION; STRAW; 400102; CHEMICAL AND SPECTRAL PROCEDURES
OSTI ID:
10113583
Research Organizations:
Pakistan Inst. of Nuclear Science and Technology, Islamabad (Pakistan). Radiation and Isotope Application Div.
Country of Origin:
Pakistan
Language:
English
Other Identifying Numbers:
Other: ON: DE95614629; TRN: PK9400124014172
Availability:
OSTI; NTIS (US Sales Only); INIS
Submitting Site:
INIS
Size:
16 p.
Announcement Date:
Jun 30, 2005

Citation Formats

Sajjad, M I, Latif, Z, Tasneem, M A, Ali, M, and Bilal, R. Standardization of /sup 13/CO/sub 2/ production procedure from organic matter for mass spectrometric analysis. Pakistan: N. p., 1993. Web.
Sajjad, M I, Latif, Z, Tasneem, M A, Ali, M, & Bilal, R. Standardization of /sup 13/CO/sub 2/ production procedure from organic matter for mass spectrometric analysis. Pakistan.
Sajjad, M I, Latif, Z, Tasneem, M A, Ali, M, and Bilal, R. 1993. "Standardization of /sup 13/CO/sub 2/ production procedure from organic matter for mass spectrometric analysis." Pakistan.
@misc{etde_10113583,
title = {Standardization of /sup 13/CO/sub 2/ production procedure from organic matter for mass spectrometric analysis}
author = {Sajjad, M I, Latif, Z, Tasneem, M A, Ali, M, and Bilal, R}
abstractNote = {This report summarizes the ways and means by which /sup 13/Co/sub 2/ production procedure from organic matter can be standardized. Optimum sample preparation conditions were determined to get reproducible results. Plant combustion for six minutes at 900-1000 degree C with pure O/sub 2/ and ten minutes for conversion of CO to CO/ sub 2/ over CUO gauze at 850 degree C have been found optimum conditions. Internal standards: PINSTECH wheat straw, PINSTECH grass sample, Glucose-D glaxo PINSTECH and polyethylene foil PINSTECH were selected, and calibrated against IAEA Sucrose and polyethylene foil standards. These internal standards have been used for correction of delta 13 C results. The mechanisms for the correction of results has been described. Causes of isotope fractionation of plant samples were determined. Statistical summary of measured results for delta /sup 13/C standards has also been given. (author).}
place = {Pakistan}
year = {1993}
month = {Nov}
}