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Determination of calcium in sodium by vacuum distillation-atomic absorption spectrophotometry

Abstract

A method for determing calcium in sodium at 2 ppm or more is described. The matrix sodium was removed by vacuum distillation at 360 deg C and 5 x 10{sup -3} Pa. The calcium in the residue was determined by atomic absorption spectrophotometry. The recovery rate of this method was satisfied in experiments of adding 2{approx}500 ppm calcium to 1{approx}4 grams of high purity sodium. The relative standard deviation was at 5.3%{approx}7.2%. The possible loss of calcium and its compound resulting from distillation had been investigated. The interference and suppressing methods were also studied.
Authors:
Ximeng, Wen; Shujuan, Su; Shiping, Sun; Jingfang, Liu; Dejun, Ding [1] 
  1. Academia Sinica, Beijing, BJ (China). Inst. of Atomic Energy
Publication Date:
Nov 01, 1990
Product Type:
Technical Report
Report Number:
CNIC-00452; IAE-0085.
Reference Number:
SCA: 400102; PA: AIX-23:010557; SN: 92000637538
Resource Relation:
Other Information: PBD: Nov 1990
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; CALCIUM; ABSORPTION SPECTROSCOPY; SODIUM; ACCURACY; DISTILLATION; HIGH VACUUM; INTERFERING ELEMENTS; 400102; CHEMICAL AND SPECTRAL PROCEDURES
OSTI ID:
10111307
Research Organizations:
China Nuclear Information Centre, Beijing, BJ (China)
Country of Origin:
China
Language:
Chinese
Other Identifying Numbers:
Other: ON: DE92613307; TRN: CN9101689010557
Availability:
OSTI; NTIS (US Sales Only); INIS
Submitting Site:
INIS
Size:
12 p.
Announcement Date:
Jun 30, 2005

Citation Formats

Ximeng, Wen, Shujuan, Su, Shiping, Sun, Jingfang, Liu, and Dejun, Ding. Determination of calcium in sodium by vacuum distillation-atomic absorption spectrophotometry. China: N. p., 1990. Web.
Ximeng, Wen, Shujuan, Su, Shiping, Sun, Jingfang, Liu, & Dejun, Ding. Determination of calcium in sodium by vacuum distillation-atomic absorption spectrophotometry. China.
Ximeng, Wen, Shujuan, Su, Shiping, Sun, Jingfang, Liu, and Dejun, Ding. 1990. "Determination of calcium in sodium by vacuum distillation-atomic absorption spectrophotometry." China.
@misc{etde_10111307,
title = {Determination of calcium in sodium by vacuum distillation-atomic absorption spectrophotometry}
author = {Ximeng, Wen, Shujuan, Su, Shiping, Sun, Jingfang, Liu, and Dejun, Ding}
abstractNote = {A method for determing calcium in sodium at 2 ppm or more is described. The matrix sodium was removed by vacuum distillation at 360 deg C and 5 x 10{sup -3} Pa. The calcium in the residue was determined by atomic absorption spectrophotometry. The recovery rate of this method was satisfied in experiments of adding 2{approx}500 ppm calcium to 1{approx}4 grams of high purity sodium. The relative standard deviation was at 5.3%{approx}7.2%. The possible loss of calcium and its compound resulting from distillation had been investigated. The interference and suppressing methods were also studied.}
place = {China}
year = {1990}
month = {Nov}
}