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Study on the extraction of Am{sup 3+} and rare earth elements with {beta}-oxime extractant (7804) (I)

Abstract

The influences of equilibrium time, temperature, pH value, extractant concentration and feed concentration on the distribution of Am{sup 3+} and rare earth elements have been studied in the extraction with {beta}-oxime extractant 7804. It was found that the optimum extraction equilibrium time is 30 min; temperature is 20 +- 1 degree C; extractant concentration is 0.2 mol/L and the pH is from 4.8 to 5.1. Under these experimental conditions, 7804 forms 2:1 complex with Am{sup 3+} or rare earth elements. The extractability sequence shows is Am>Eu>Sm>Nd>Pr>Ce>La.
Authors:
Ruiqin, Hou; Rongzhou, Jiao; Yongjun, Zhu [1] 
  1. Qinghua Univ., Beijing, BJ (China). Inst. of Nuclear Energy Technology
Publication Date:
Nov 01, 1993
Product Type:
Technical Report
Report Number:
CNIC-00793; TSHUNE-0071.
Reference Number:
SCA: 400105; 052001; PA: AIX-26:009488; EDB-95:030031; SN: 95001323100
Resource Relation:
Other Information: PBD: Nov 1993
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; 12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE WASTES FROM NUCLEAR FACILITIES; AMERICIUM COMPOUNDS; SOLVENT EXTRACTION; OXIMES; RARE EARTH COMPOUNDS; CONCENTRATION RATIO; DISTRIBUTION FUNCTIONS; PH VALUE; TEMPERATURE DEPENDENCE; 400105; 052001; SEPARATION PROCEDURES; WASTE PROCESSING
OSTI ID:
10111259
Research Organizations:
China Nuclear Information Centre, Beijing, BJ (China)
Country of Origin:
China
Language:
Chinese
Other Identifying Numbers:
Other: ON: DE95611881; ISBN 7-5022-1084-9; TRN: CN9402336009488
Availability:
OSTI; NTIS (US Sales Only); INIS
Submitting Site:
INIS
Size:
8 p.
Announcement Date:
Jun 30, 2005

Citation Formats

Ruiqin, Hou, Rongzhou, Jiao, and Yongjun, Zhu. Study on the extraction of Am{sup 3+} and rare earth elements with {beta}-oxime extractant (7804) (I). China: N. p., 1993. Web.
Ruiqin, Hou, Rongzhou, Jiao, & Yongjun, Zhu. Study on the extraction of Am{sup 3+} and rare earth elements with {beta}-oxime extractant (7804) (I). China.
Ruiqin, Hou, Rongzhou, Jiao, and Yongjun, Zhu. 1993. "Study on the extraction of Am{sup 3+} and rare earth elements with {beta}-oxime extractant (7804) (I)." China.
@misc{etde_10111259,
title = {Study on the extraction of Am{sup 3+} and rare earth elements with {beta}-oxime extractant (7804) (I)}
author = {Ruiqin, Hou, Rongzhou, Jiao, and Yongjun, Zhu}
abstractNote = {The influences of equilibrium time, temperature, pH value, extractant concentration and feed concentration on the distribution of Am{sup 3+} and rare earth elements have been studied in the extraction with {beta}-oxime extractant 7804. It was found that the optimum extraction equilibrium time is 30 min; temperature is 20 +- 1 degree C; extractant concentration is 0.2 mol/L and the pH is from 4.8 to 5.1. Under these experimental conditions, 7804 forms 2:1 complex with Am{sup 3+} or rare earth elements. The extractability sequence shows is Am>Eu>Sm>Nd>Pr>Ce>La.}
place = {China}
year = {1993}
month = {Nov}
}