This study has been focused on the development of an indigenous partitioning process by modifying and complementing the reported processes. First of all, we tried to approach several unit separation processes in order to identify their adoptability to the partitioning of long-lived radionuclides. There are several unit separation methods - adsorption, precipitation, ion exchange, and solvent extraction etc. which are often used in ore processing or metal purification processes. With the unit processes chosen in this study, the following experiments have been carried out to provide technical facts necessary to develop a partitioning process. (1) Removal of a small amount of uranium by extraction with TBP from simulated waste solution (2) Destruction of nitric acid by use of formic acid (3) Co-precipitation of minor actinides and lanthanides. (4) Partitioning of minor actinides and lanthanides by extraction with HDEHP (5) Partitioning of minor actinides and lanthanides by ion exchange.