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Electrocatalytic oxidations of pyridine derivatives using Ru(IV) poly pyridine complex; Oxidacoes eletrocataliticas de derivados de piridina utilizando um complexo polipiridinico de Ru(IV)

Abstract

The oxidation reactions electro catalysed by bi pyridine oxo tri pyridine ruthenium perchlorate metallic complex from selected organic substrates are studied. The obtained results are compared with forecasting results showing the coherence of suggested mechanism. The substrates 2-, 2- and 4- picolines with its respective 1-oxides and 1,2 -; 1,3 - and 1,4 - dimethyl pyridine chloride salts were analysed. The oxidation of toluene as reference substrate was also studied and the mass spectra of oxidation products were interpreted. (M.C.K.).
Publication Date:
Dec 31, 1989
Product Type:
Thesis/Dissertation
Report Number:
INIS-BR-3067
Reference Number:
SCA: 400201; PA: AIX-24:000090; SN: 93000912540
Resource Relation:
Other Information: TH: Tese (M.Sc.).; PBD: 1989
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; RUTHENIUM COMPLEXES; CHEMICAL REACTION KINETICS; OXIDATION; CATALYSIS; MASS SPECTRA; PYRIDINES; TOLUENE; 400201; CHEMICAL AND PHYSICOCHEMICAL PROPERTIES
OSTI ID:
10108450
Research Organizations:
Sao Paulo Univ., Ribeirao Preto, SP (Brazil). Faculdade de Filosofia, Ciencias e Letras
Country of Origin:
Brazil
Language:
Portuguese
Other Identifying Numbers:
Other: ON: DE93608800; TRN: BR9230448000090
Availability:
OSTI; NTIS (US Sales Only); INIS
Submitting Site:
INIS
Size:
[72] p.
Announcement Date:
Jun 30, 2005

Citation Formats

Oliveira, S.M. de. Electrocatalytic oxidations of pyridine derivatives using Ru(IV) poly pyridine complex; Oxidacoes eletrocataliticas de derivados de piridina utilizando um complexo polipiridinico de Ru(IV). Brazil: N. p., 1989. Web.
Oliveira, S.M. de. Electrocatalytic oxidations of pyridine derivatives using Ru(IV) poly pyridine complex; Oxidacoes eletrocataliticas de derivados de piridina utilizando um complexo polipiridinico de Ru(IV). Brazil.
Oliveira, S.M. de. 1989. "Electrocatalytic oxidations of pyridine derivatives using Ru(IV) poly pyridine complex; Oxidacoes eletrocataliticas de derivados de piridina utilizando um complexo polipiridinico de Ru(IV)." Brazil.
@misc{etde_10108450,
title = {Electrocatalytic oxidations of pyridine derivatives using Ru(IV) poly pyridine complex; Oxidacoes eletrocataliticas de derivados de piridina utilizando um complexo polipiridinico de Ru(IV)}
author = {Oliveira, S.M. de}
abstractNote = {The oxidation reactions electro catalysed by bi pyridine oxo tri pyridine ruthenium perchlorate metallic complex from selected organic substrates are studied. The obtained results are compared with forecasting results showing the coherence of suggested mechanism. The substrates 2-, 2- and 4- picolines with its respective 1-oxides and 1,2 -; 1,3 - and 1,4 - dimethyl pyridine chloride salts were analysed. The oxidation of toluene as reference substrate was also studied and the mass spectra of oxidation products were interpreted. (M.C.K.).}
place = {Brazil}
year = {1989}
month = {Dec}
}