You need JavaScript to view this

Radiolytic electron transfer in cobaloximes

Conference:

Abstract

Chloro(pyridine [bis(dimethylglyoximato)] Co(III) and alkyl(pyridine[bis(dimethylglyoximato)]Co(III) were reduced by solvated electrons and by other reducing radicals in irradiated solutions under different conditions. These complexes were reduced to Co(II) state initially. Further reduction gave the Co(I) state, which was stable under anaerobic conditions but only in alkaline solutions, in the case of Cl(py) (dmg){sub 2}Co(III). (author). 7 refs.
Authors:
Kumar, Manmohan; Neta, P [1] 
  1. National Institute of Standards and Technology, Gaithersburg (United States)
Publication Date:
Dec 31, 1994
Product Type:
Conference
Report Number:
CONF-9401116-
Reference Number:
SCA: 400600; PA: AIX-26:062485; EDB-95:131135; SN: 95001457655
Resource Relation:
Conference: TRSP-94: Trombay symposium on radiation and photochemistry, Bombay (India), 17-21 Jan 1994; Other Information: PBD: 1994; Related Information: Is Part Of Trombay symposium on radiation and photochemistry. Preprints vol.2: contributed papers; PB: 407 p.
Subject:
40 CHEMISTRY; COBALT COMPLEXES; RADIOLYSIS; ALKYL RADICALS; CHEMICAL REACTION KINETICS; COBALT 60; ELECTRON BEAMS; ELECTRON TRANSFER; GAMMA RADIATION; HYDRATION; ORGANIC CHLORINE COMPOUNDS; OXIMES; PULSED IRRADIATION; PYRIDINES; REDUCTION; SOLVATED ELECTRONS
OSTI ID:
101066
Research Organizations:
Department of Atomic Energy, Bombay (India). Board of Research in Nuclear Sciences
Country of Origin:
India
Language:
English
Other Identifying Numbers:
TRN: IN9501081062485
Submitting Site:
INIS
Size:
pp. 13-15
Announcement Date:
Jan 16, 2004

Conference:

Citation Formats

Kumar, Manmohan, and Neta, P. Radiolytic electron transfer in cobaloximes. India: N. p., 1994. Web.
Kumar, Manmohan, & Neta, P. Radiolytic electron transfer in cobaloximes. India.
Kumar, Manmohan, and Neta, P. 1994. "Radiolytic electron transfer in cobaloximes." India.
@misc{etde_101066,
title = {Radiolytic electron transfer in cobaloximes}
author = {Kumar, Manmohan, and Neta, P}
abstractNote = {Chloro(pyridine [bis(dimethylglyoximato)] Co(III) and alkyl(pyridine[bis(dimethylglyoximato)]Co(III) were reduced by solvated electrons and by other reducing radicals in irradiated solutions under different conditions. These complexes were reduced to Co(II) state initially. Further reduction gave the Co(I) state, which was stable under anaerobic conditions but only in alkaline solutions, in the case of Cl(py) (dmg){sub 2}Co(III). (author). 7 refs.}
place = {India}
year = {1994}
month = {Dec}
}