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Charged hard spheres in a uniform neutralizing background: The role of thermodynamics selfconsistence

Technical Report:

Abstract

Calculations of the thermodynamic properties and pair distribution function of a one-component classical fluid of charged hard spheres in a uniform neutralizing background are reported and compared with Monte Carlo results of Hansen and Weis. Thermodynamic selfconsistence between the virial pressure and the fluctuations formula for the isothermal compressibility is enforced in the calculations by various alternative approaches. The role of thermodynamic selfconsistence is crucial to obtain a satisfactory quantitative description of this model fluid, in view of its applications in the theory of liquid metals and of dispersions of charged colloidal particles. (author). 23 refs, 4 figs, 3 tabs.
Authors:
Badirkhan, Z; [1]  Pastore, G; Tosi, M P [2] 
  1. International Centre for Theoretical Physics, Trieste (Italy)
  2. Trieste Univ. (Italy). Ist. di Fisica Teorica
Publication Date:
Jun 01, 1991
Product Type:
Technical Report
Report Number:
IC-91/113
Reference Number:
SCA: 665000; PA: AIX-22:081831; SN: 91000608922
Resource Relation:
Other Information: PBD: Jun 1991
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; FLUIDS; THERMODYNAMIC PROPERTIES; DISTRIBUTION FUNCTIONS; STRUCTURE FACTORS; 665000; PHYSICS OF CONDENSED MATTER
OSTI ID:
10105063
Research Organizations:
International Centre for Theoretical Physics (ICTP), Trieste (Italy)
Country of Origin:
IAEA
Language:
English
Other Identifying Numbers:
Other: ON: DE92609233; TRN: XA9129638081831
Availability:
OSTI; NTIS (US Sales Only); INIS
Submitting Site:
INIS
Size:
16 p.
Announcement Date:
Jun 30, 2005

Technical Report:

Citation Formats

Badirkhan, Z, Pastore, G, and Tosi, M P. Charged hard spheres in a uniform neutralizing background: The role of thermodynamics selfconsistence. IAEA: N. p., 1991. Web.
Badirkhan, Z, Pastore, G, & Tosi, M P. Charged hard spheres in a uniform neutralizing background: The role of thermodynamics selfconsistence. IAEA.
Badirkhan, Z, Pastore, G, and Tosi, M P. 1991. "Charged hard spheres in a uniform neutralizing background: The role of thermodynamics selfconsistence." IAEA.
@misc{etde_10105063,
title = {Charged hard spheres in a uniform neutralizing background: The role of thermodynamics selfconsistence}
author = {Badirkhan, Z, Pastore, G, and Tosi, M P}
abstractNote = {Calculations of the thermodynamic properties and pair distribution function of a one-component classical fluid of charged hard spheres in a uniform neutralizing background are reported and compared with Monte Carlo results of Hansen and Weis. Thermodynamic selfconsistence between the virial pressure and the fluctuations formula for the isothermal compressibility is enforced in the calculations by various alternative approaches. The role of thermodynamic selfconsistence is crucial to obtain a satisfactory quantitative description of this model fluid, in view of its applications in the theory of liquid metals and of dispersions of charged colloidal particles. (author). 23 refs, 4 figs, 3 tabs.}
place = {IAEA}
year = {1991}
month = {Jun}
}