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Reactions between cerium(IV) and methyl-6-x-derivatives of aniline in perchloric acid solutions

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Abstract

The oxidation of 2,6-dimethyl-, 2-isopropyl-6-methyl, 2-chloro-6-methyl-and 2-methyl-6-nitro aniline with cerium(IV) in perchloric acid solutions has been examined. It has been found that the concentration of hydrogen ions and the basicity of nitrogen atom in the amine group decide about the resultant intermediate products. Some of these products can be practically prepared using cerium(IV) as an oxidizing agent. (author). 16 refs, 1 tab.
Authors:
Dziegiec, J [1] 
  1. Lodz Univ. (Poland)
Publication Date:
Dec 31, 1994
Product Type:
Journal Article
Reference Number:
SCA: 400201; PA: AIX-26:062415; EDB-95:131024; SN: 95001457619
Resource Relation:
Journal Name: Polish Journal of Applied Chemistry; Journal Volume: 38; Journal Issue: 1; Other Information: PBD: 1994
Subject:
40 CHEMISTRY; ANILINE; REDOX REACTIONS; CERIUM IONS; CHEMICAL REACTION KINETICS; PERCHLORIC ACID; REACTION INTERMEDIATES
OSTI ID:
100490
Country of Origin:
Poland
Language:
English
Other Identifying Numbers:
Journal ID: PJACE2; TRN: PL9500287062415
Submitting Site:
PLN
Size:
pp. 43-48
Announcement Date:
Oct 04, 1995

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Citation Formats

Dziegiec, J. Reactions between cerium(IV) and methyl-6-x-derivatives of aniline in perchloric acid solutions. Poland: N. p., 1994. Web.
Dziegiec, J. Reactions between cerium(IV) and methyl-6-x-derivatives of aniline in perchloric acid solutions. Poland.
Dziegiec, J. 1994. "Reactions between cerium(IV) and methyl-6-x-derivatives of aniline in perchloric acid solutions." Poland.
@misc{etde_100490,
title = {Reactions between cerium(IV) and methyl-6-x-derivatives of aniline in perchloric acid solutions}
 author = {Dziegiec, J}
 abstractNote = {The oxidation of 2,6-dimethyl-, 2-isopropyl-6-methyl, 2-chloro-6-methyl-and 2-methyl-6-nitro aniline with cerium(IV) in perchloric acid solutions has been examined. It has been found that the concentration of hydrogen ions and the basicity of nitrogen atom in the amine group decide about the resultant intermediate products. Some of these products can be practically prepared using cerium(IV) as an oxidizing agent. (author). 16 refs, 1 tab.}
 journal = []
 issue = {1}
 volume = {38}
 journal type = {AC}
 place = {Poland}
 year = {1994}
 month = {Dec}
 }