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Effect of gamma irradiation on some important extractants of divalent palladium

Conference:

Abstract

Four reagents, tri-isobutylphosphine sulphide (TIPS), alpha benzoin oxime (ABO), dioctylsulphide (DOS) and dioctylsulphoxide (DOSO), of relevance to the extraction and recovery of palladium from high radioactive waste solutions of PUREX origin, have been irradiated at different gamma doses. These irradiated reagents as such and also after washing with 0.2 M sodium carbonate solution have been utilised from the extraction of Pd(II). The results of the extraction behaviour of palladium with the irradiated reagents and its stripping from the loaded organic phase have been discussed. (author). 4 refs., 2 tabs.
Authors:
Murali, M S; Rizvi, G H; Mathur, J N; Iyer, R H; [1]  Dakkshinamoorthy, A; Singh, R K [2] 
  1. Bhabha Atomic Research Centre, Bombay (India). Radiochemistry Div.
  2. Bhabha Atomic Research Centre, Bombay (India). PREFRE
Publication Date:
Dec 31, 1994
Product Type:
Conference
Report Number:
CONF-9401116-
Reference Number:
SCA: 400600; PA: AIX-26:062502; EDB-95:131132; SN: 95001457672
Resource Relation:
Conference: TRSP-94: Trombay symposium on radiation and photochemistry, Bombay (India), 17-21 Jan 1994; Other Information: PBD: 1994; Related Information: Is Part Of Trombay symposium on radiation and photochemistry. Preprints vol.2: contributed papers; PB: 407 p.
Subject:
40 CHEMISTRY; LIGANDS; CHEMICAL RADIATION EFFECTS; PALLADIUM; SOLVENT EXTRACTION; AMMONIUM CHLORIDES; COBALT 60; DISTRIBUTION FUNCTIONS; DOSE-RESPONSE RELATIONSHIPS; GAMMA RADIATION; HIGH-LEVEL RADIOACTIVE WASTES; NITRIC ACID; OXIMES; PALLADIUM CHLORIDES; PHOSPHINES; PUREX PROCESS; SODIUM CARBONATES; SULFIDES; SULFOXIDES
OSTI ID:
100385
Research Organizations:
Department of Atomic Energy, Bombay (India). Board of Research in Nuclear Sciences
Country of Origin:
India
Language:
English
Other Identifying Numbers:
TRN: IN9501098062502
Submitting Site:
INIS
Size:
pp. 66-68
Announcement Date:
Jan 16, 2004

Conference:

Citation Formats

Murali, M S, Rizvi, G H, Mathur, J N, Iyer, R H, Dakkshinamoorthy, A, and Singh, R K. Effect of gamma irradiation on some important extractants of divalent palladium. India: N. p., 1994. Web.
Murali, M S, Rizvi, G H, Mathur, J N, Iyer, R H, Dakkshinamoorthy, A, & Singh, R K. Effect of gamma irradiation on some important extractants of divalent palladium. India.
Murali, M S, Rizvi, G H, Mathur, J N, Iyer, R H, Dakkshinamoorthy, A, and Singh, R K. 1994. "Effect of gamma irradiation on some important extractants of divalent palladium." India.
@misc{etde_100385,
title = {Effect of gamma irradiation on some important extractants of divalent palladium}
author = {Murali, M S, Rizvi, G H, Mathur, J N, Iyer, R H, Dakkshinamoorthy, A, and Singh, R K}
abstractNote = {Four reagents, tri-isobutylphosphine sulphide (TIPS), alpha benzoin oxime (ABO), dioctylsulphide (DOS) and dioctylsulphoxide (DOSO), of relevance to the extraction and recovery of palladium from high radioactive waste solutions of PUREX origin, have been irradiated at different gamma doses. These irradiated reagents as such and also after washing with 0.2 M sodium carbonate solution have been utilised from the extraction of Pd(II). The results of the extraction behaviour of palladium with the irradiated reagents and its stripping from the loaded organic phase have been discussed. (author). 4 refs., 2 tabs.}
place = {India}
year = {1994}
month = {Dec}
}