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One electron oxidation of triphenyl methane dyes, crystal violet and malachite green by N{sub 3}{sup .} and Br{sub 2}{sup -}

Abstract

The kinetics of formation and the transient spectra of the species arising due to the oxidation of CV{sup +} and MG{sup +} by N{sub 3}{sup .} and Br{sub 2}{sup -} have been determined. The time resolved spectra indicate intermediate adduct formation between N{sub 3}{sup .}/Br{sub 2}{sup -} and CV{sup +}. (author). 1 ref., 2 figs.
Authors:
Bhasikuttan, A C; Sapre, A V; Shastri, L V; Rama Rao, K V.S. [1] 
  1. Bhabha Atomic Research Centre, Bombay (India). Chemistry Div.
Publication Date:
Dec 31, 1994
Product Type:
Conference
Report Number:
CONF-9401116-
Reference Number:
SCA: 400600; PA: AIX-26:062500; EDB-95:131117; SN: 95001457670
Resource Relation:
Conference: TRSP-94: Trombay symposium on radiation and photochemistry, Bombay (India), 17-21 Jan 1994; Other Information: PBD: 1994; Related Information: Is Part Of Trombay symposium on radiation and photochemistry. Preprints vol.2: contributed papers; PB: 407 p.
Subject:
40 CHEMISTRY; TRIPHENYLMETHANE DYES; RADIOLYSIS; ABSORPTION SPECTRA; ANIONS; BROMINE; CHEMICAL REACTION KINETICS; ELECTRON BEAMS; NITROGEN OXIDES; OXIDATION; POTASSIUM BROMIDES; PULSED IRRADIATION; RADICALS
OSTI ID:
100383
Research Organizations:
Department of Atomic Energy, Bombay (India). Board of Research in Nuclear Sciences
Country of Origin:
India
Language:
English
Other Identifying Numbers:
TRN: IN9501096062500
Submitting Site:
INIS
Size:
pp. 61-63
Announcement Date:
Jan 16, 2004

Citation Formats

Bhasikuttan, A C, Sapre, A V, Shastri, L V, and Rama Rao, K V.S. One electron oxidation of triphenyl methane dyes, crystal violet and malachite green by N{sub 3}{sup .} and Br{sub 2}{sup -}. India: N. p., 1994. Web.
Bhasikuttan, A C, Sapre, A V, Shastri, L V, & Rama Rao, K V.S. One electron oxidation of triphenyl methane dyes, crystal violet and malachite green by N{sub 3}{sup .} and Br{sub 2}{sup -}. India.
Bhasikuttan, A C, Sapre, A V, Shastri, L V, and Rama Rao, K V.S. 1994. "One electron oxidation of triphenyl methane dyes, crystal violet and malachite green by N{sub 3}{sup .} and Br{sub 2}{sup -}." India.
@misc{etde_100383,
title = {One electron oxidation of triphenyl methane dyes, crystal violet and malachite green by N{sub 3}{sup .} and Br{sub 2}{sup -}}
author = {Bhasikuttan, A C, Sapre, A V, Shastri, L V, and Rama Rao, K V.S.}
abstractNote = {The kinetics of formation and the transient spectra of the species arising due to the oxidation of CV{sup +} and MG{sup +} by N{sub 3}{sup .} and Br{sub 2}{sup -} have been determined. The time resolved spectra indicate intermediate adduct formation between N{sub 3}{sup .}/Br{sub 2}{sup -} and CV{sup +}. (author). 1 ref., 2 figs.}
place = {India}
year = {1994}
month = {Dec}
}