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One electron reduction of triphenyl methane dyes by hydrated electrons

Abstract

Electron reaction rates for the triphenylmethane (TPM) dyes have been evaluated. Spectral characteristics of the resulting dye radicals have been determined. Evolution of the transient spectra shows intramolecular rearrangement in the radical from brilliant green and malachite green. (author). 3 refs., 1 fig., 1 tab.
Authors:
Bhasikuttan, A C; Shastri, L V; Sapre, A V; Rama Rao, K V.S. [1] 
  1. Bhabha Atomic Research Centre, Bombay (India). Chemistry Div.
Publication Date:
Dec 31, 1994
Product Type:
Conference
Report Number:
CONF-9401116-
Reference Number:
SCA: 400600; PA: AIX-26:062499; EDB-95:131130; SN: 95001457669
Resource Relation:
Conference: TRSP-94: Trombay symposium on radiation and photochemistry, Bombay (India), 17-21 Jan 1994; Other Information: PBD: 1994; Related Information: Is Part Of Trombay symposium on radiation and photochemistry. Preprints vol.2: contributed papers; PB: 407 p.
Subject:
40 CHEMISTRY; TRIPHENYLMETHANE DYES; RADIOLYSIS; ABSORPTION SPECTRA; CHEMICAL REACTION KINETICS; ELECTRON BEAMS; HYDRATION; PULSED IRRADIATION; REDUCTION; SOLVATED ELECTRONS
OSTI ID:
100382
Research Organizations:
Department of Atomic Energy, Bombay (India). Board of Research in Nuclear Sciences
Country of Origin:
India
Language:
English
Other Identifying Numbers:
TRN: IN9501095062499
Submitting Site:
INIS
Size:
pp. 58-60
Announcement Date:
Jan 16, 2004

Citation Formats

Bhasikuttan, A C, Shastri, L V, Sapre, A V, and Rama Rao, K V.S. One electron reduction of triphenyl methane dyes by hydrated electrons. India: N. p., 1994. Web.
Bhasikuttan, A C, Shastri, L V, Sapre, A V, & Rama Rao, K V.S. One electron reduction of triphenyl methane dyes by hydrated electrons. India.
Bhasikuttan, A C, Shastri, L V, Sapre, A V, and Rama Rao, K V.S. 1994. "One electron reduction of triphenyl methane dyes by hydrated electrons." India.
@misc{etde_100382,
title = {One electron reduction of triphenyl methane dyes by hydrated electrons}
author = {Bhasikuttan, A C, Shastri, L V, Sapre, A V, and Rama Rao, K V.S.}
abstractNote = {Electron reaction rates for the triphenylmethane (TPM) dyes have been evaluated. Spectral characteristics of the resulting dye radicals have been determined. Evolution of the transient spectra shows intramolecular rearrangement in the radical from brilliant green and malachite green. (author). 3 refs., 1 fig., 1 tab.}
place = {India}
year = {1994}
month = {Dec}
}