Abstract
The initial e{sub aq}{sup -}/H adducts of 2-mercapto benzimidazole(MBZ) ({lambda}{sub max} {approx} 370 nm) which are mild reductants react with parent compound to give an intermolecular 3-electron bonded species with {lambda}{sub max} at 590 nm. The rate constants for the reactions of MBZ with e{sub aq}{sup -} and OH radicals at pH 7 and with H-atoms at pH 2 were determined. OH radical reaction with MBZ gives an intramolecular 3-electron bonded species. (author). 2 refs., 2 figs., 1 tab.
Dey, G R;
Naik, D B;
Kishore, K;
Moorthy, P N
[1]
- Bhabha Atomic Research Centre, Bombay (India). Applied Chemistry Division
Citation Formats
Dey, G R, Naik, D B, Kishore, K, and Moorthy, P N.
Pulse radiolysis of 2-mercapto benzimidazole in aqueous solutions.
India: N. p.,
1994.
Web.
Dey, G R, Naik, D B, Kishore, K, & Moorthy, P N.
Pulse radiolysis of 2-mercapto benzimidazole in aqueous solutions.
India.
Dey, G R, Naik, D B, Kishore, K, and Moorthy, P N.
1994.
"Pulse radiolysis of 2-mercapto benzimidazole in aqueous solutions."
India.
@misc{etde_100376,
title = {Pulse radiolysis of 2-mercapto benzimidazole in aqueous solutions}
author = {Dey, G R, Naik, D B, Kishore, K, and Moorthy, P N}
abstractNote = {The initial e{sub aq}{sup -}/H adducts of 2-mercapto benzimidazole(MBZ) ({lambda}{sub max} {approx} 370 nm) which are mild reductants react with parent compound to give an intermolecular 3-electron bonded species with {lambda}{sub max} at 590 nm. The rate constants for the reactions of MBZ with e{sub aq}{sup -} and OH radicals at pH 7 and with H-atoms at pH 2 were determined. OH radical reaction with MBZ gives an intramolecular 3-electron bonded species. (author). 2 refs., 2 figs., 1 tab.}
place = {India}
year = {1994}
month = {Dec}
}
title = {Pulse radiolysis of 2-mercapto benzimidazole in aqueous solutions}
author = {Dey, G R, Naik, D B, Kishore, K, and Moorthy, P N}
abstractNote = {The initial e{sub aq}{sup -}/H adducts of 2-mercapto benzimidazole(MBZ) ({lambda}{sub max} {approx} 370 nm) which are mild reductants react with parent compound to give an intermolecular 3-electron bonded species with {lambda}{sub max} at 590 nm. The rate constants for the reactions of MBZ with e{sub aq}{sup -} and OH radicals at pH 7 and with H-atoms at pH 2 were determined. OH radical reaction with MBZ gives an intramolecular 3-electron bonded species. (author). 2 refs., 2 figs., 1 tab.}
place = {India}
year = {1994}
month = {Dec}
}