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Redox reactions of azulene-{beta}-cyclodextrin inclusion complex

Conference:

Abstract

Redox reactions of azulene (AZ) with H{sup .}, {sup .}OH, e{sub aq}{sup -} and N{sub 3}{sup .} in aqueous medium were studied using the technique of pulse radiolysis and the results were compared with AZ-{beta}-cyclodextrin ({beta}-CD) complex in water. In the latter case ({beta}-CD/AZ complex) the lifetime of AZ{sub aq}{sup -}increased by an order and AZ{sup +} absorbance showed 50% increase with N{sub 3}{sup .} as the oxidant. (author). 2 refs., 3 figs., 1 tab.
Authors:
Priyadarsini, K I; Das, T N [1] 
  1. Bhabha Atomic Research Centre, Bombay (India). Chemistry Division
Publication Date:
Dec 31, 1994
Product Type:
Conference
Report Number:
CONF-9401116-
Reference Number:
SCA: 400600; PA: AIX-26:062492; EDB-95:131133; SN: 95001457662
Resource Relation:
Conference: TRSP-94: Trombay symposium on radiation and photochemistry, Bombay (India), 17-21 Jan 1994; Other Information: PBD: 1994; Related Information: Is Part Of Trombay symposium on radiation and photochemistry. Preprints vol.2: contributed papers; PB: 407 p.
Subject:
40 CHEMISTRY; AZULENE; RADIOLYSIS; REDOX REACTIONS; ABSORPTION SPECTRA; AQUEOUS SOLUTIONS; DEXTRIN; ELECTRON BEAMS; HYDROXYL RADICALS; PULSED IRRADIATION; SOLVATED ELECTRONS
OSTI ID:
100374
Research Organizations:
Department of Atomic Energy, Bombay (India). Board of Research in Nuclear Sciences
Country of Origin:
India
Language:
English
Other Identifying Numbers:
TRN: IN9501088062492
Submitting Site:
INIS
Size:
pp. 34-36
Announcement Date:
Jan 16, 2004

Conference:

Citation Formats

Priyadarsini, K I, and Das, T N. Redox reactions of azulene-{beta}-cyclodextrin inclusion complex. India: N. p., 1994. Web.
Priyadarsini, K I, & Das, T N. Redox reactions of azulene-{beta}-cyclodextrin inclusion complex. India.
Priyadarsini, K I, and Das, T N. 1994. "Redox reactions of azulene-{beta}-cyclodextrin inclusion complex." India.
@misc{etde_100374,
title = {Redox reactions of azulene-{beta}-cyclodextrin inclusion complex}
author = {Priyadarsini, K I, and Das, T N}
abstractNote = {Redox reactions of azulene (AZ) with H{sup .}, {sup .}OH, e{sub aq}{sup -} and N{sub 3}{sup .} in aqueous medium were studied using the technique of pulse radiolysis and the results were compared with AZ-{beta}-cyclodextrin ({beta}-CD) complex in water. In the latter case ({beta}-CD/AZ complex) the lifetime of AZ{sub aq}{sup -}increased by an order and AZ{sup +} absorbance showed 50% increase with N{sub 3}{sup .} as the oxidant. (author). 2 refs., 3 figs., 1 tab.}
place = {India}
year = {1994}
month = {Dec}
}