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Pulse radiolysis investigations on OH radical induced reactions with bromobenzene in aqueous solutions

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Abstract

The transient optical absorption band ({lambda}{sub max} = 325 nm), formed on reaction of OH radicals in neutral aqueous solutions of bromobenzene is assigned to OH-adduct with benzene ring. In acidic solutions, transient bands with {lambda}{sub max} = 320 and 540 nm are assigned to solute radical cation formed on electron transfer from benzene ring and Br respectively. (author). 1 ref., 2 figs.
Authors:
Mohan, Hari [1] 
  1. Bhabha Atomic Research Centre, Bombay (India). Chemistry Division
Publication Date:
Dec 31, 1994
Product Type:
Conference
Report Number:
CONF-9401116-
Reference Number:
SCA: 400600; PA: AIX-26:062486; EDB-95:131120; SN: 95001457656
Resource Relation:
Conference: TRSP-94: Trombay symposium on radiation and photochemistry, Bombay (India), 17-21 Jan 1994; Other Information: PBD: 1994; Related Information: Is Part Of Trombay symposium on radiation and photochemistry. Preprints vol.2: contributed papers; PB: 407 p.
Subject:
40 CHEMISTRY; BROMINATED AROMATIC HYDROCARBONS; RADIOLYSIS; AQUEOUS SOLUTIONS; BENZENE; CHEMICAL REACTION KINETICS; ELECTRON BEAMS; ELECTRON TRANSFER; HYDROXYL RADICALS; PULSED IRRADIATION
OSTI ID:
100366
Research Organizations:
Department of Atomic Energy, Bombay (India). Board of Research in Nuclear Sciences
Country of Origin:
India
Language:
English
Other Identifying Numbers:
TRN: IN9501082062486
Submitting Site:
INIS
Size:
pp. 16-18
Announcement Date:
Jan 16, 2004

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Citation Formats

Mohan, Hari. Pulse radiolysis investigations on OH radical induced reactions with bromobenzene in aqueous solutions. India: N. p., 1994. Web.
Mohan, Hari. Pulse radiolysis investigations on OH radical induced reactions with bromobenzene in aqueous solutions. India.
Mohan, Hari. 1994. "Pulse radiolysis investigations on OH radical induced reactions with bromobenzene in aqueous solutions." India.
@misc{etde_100366,
title = {Pulse radiolysis investigations on OH radical induced reactions with bromobenzene in aqueous solutions}
 author = {Mohan, Hari}
 abstractNote = {The transient optical absorption band ({lambda}{sub max} = 325 nm), formed on reaction of OH radicals in neutral aqueous solutions of bromobenzene is assigned to OH-adduct with benzene ring. In acidic solutions, transient bands with {lambda}{sub max} = 320 and 540 nm are assigned to solute radical cation formed on electron transfer from benzene ring and Br respectively. (author). 1 ref., 2 figs.}
 place = {India}
 year = {1994}
 month = {Dec}
 }