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Reactions of {sup .}OH and SO{sub 4}{sup .-} radicals with bromobenzenes and bromotoluenes in aqueous solution studied by pulse radiolysis

Conference:

Abstract

The absorption spectra obtained in the reactions of {sup .}OH and SO{sub 4}{sup .-}with bromobenzenes and bromotoluenes have maxima around 320 - 330 nm which are assigned to their {sup .}OH adducts. Additional weak bands (400 - 430 nm) observed in the case of SO{sub 4}{sup .-} reaction with bromobenzene and 1,2-dibromobenzene are, probably, due to the formation of the intermediate phenoxyl radical. (author). 4 refs., 1 tab., 1 fig.
Authors:
Merga, Getahun; Rao, B S.M.; [1]  Mohan, H [2] 
  1. Poona Univ., Pune (India). Dept. of Physics
  2. Bhabha Atomic Research Centre, Bombay (India). Chemistry Div.
Publication Date:
Dec 31, 1994
Product Type:
Conference
Report Number:
CONF-9401116-
Reference Number:
SCA: 400600; PA: AIX-26:062483; EDB-95:131129; SN: 95001457653
Resource Relation:
Conference: TRSP-94: Trombay symposium on radiation and photochemistry, Bombay (India), 17-21 Jan 1994; Other Information: PBD: 1994; Related Information: Is Part Of Trombay symposium on radiation and photochemistry. Preprints vol.2: contributed papers; PB: 407 p.
Subject:
40 CHEMISTRY; BROMINATED AROMATIC HYDROCARBONS; PULSED IRRADIATION; RADIOLYSIS; ABSORPTION SPECTRA; AQUEOUS SOLUTIONS; BENZENE; CHEMICAL REACTION KINETICS; ELECTRON BEAMS; HYDROXYL RADICALS; SULFATES; TOLUENE
OSTI ID:
100360
Research Organizations:
Department of Atomic Energy, Bombay (India). Board of Research in Nuclear Sciences
Country of Origin:
India
Language:
English
Other Identifying Numbers:
TRN: IN9501079062483
Submitting Site:
INIS
Size:
pp. 7-9
Announcement Date:
Jan 16, 2004

Conference:

Citation Formats

Merga, Getahun, Rao, B S.M., and Mohan, H. Reactions of {sup .}OH and SO{sub 4}{sup .-} radicals with bromobenzenes and bromotoluenes in aqueous solution studied by pulse radiolysis. India: N. p., 1994. Web.
Merga, Getahun, Rao, B S.M., & Mohan, H. Reactions of {sup .}OH and SO{sub 4}{sup .-} radicals with bromobenzenes and bromotoluenes in aqueous solution studied by pulse radiolysis. India.
Merga, Getahun, Rao, B S.M., and Mohan, H. 1994. "Reactions of {sup .}OH and SO{sub 4}{sup .-} radicals with bromobenzenes and bromotoluenes in aqueous solution studied by pulse radiolysis." India.
@misc{etde_100360,
title = {Reactions of {sup .}OH and SO{sub 4}{sup .-} radicals with bromobenzenes and bromotoluenes in aqueous solution studied by pulse radiolysis}
author = {Merga, Getahun, Rao, B S.M., and Mohan, H}
abstractNote = {The absorption spectra obtained in the reactions of {sup .}OH and SO{sub 4}{sup .-}with bromobenzenes and bromotoluenes have maxima around 320 - 330 nm which are assigned to their {sup .}OH adducts. Additional weak bands (400 - 430 nm) observed in the case of SO{sub 4}{sup .-} reaction with bromobenzene and 1,2-dibromobenzene are, probably, due to the formation of the intermediate phenoxyl radical. (author). 4 refs., 1 tab., 1 fig.}
place = {India}
year = {1994}
month = {Dec}
}