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Radiation chemical oxidation of substituted benzenes by Cl{sub 2}{sup .-}

Conference:

Abstract

Reaction of Cl{sub 2}{sup .-} radical with chloro, methyl and methoxylated benzenes was studied by pulse radiolysis in acidic condition. The rate of Cl{sub 2}{sup .-} reaction with chlorobenzene, toluene and chlorotoluene was lower (0.8 - 15 x 10{sup 6} dm{sup 3} mol{sup -1} s{sup -1}), however, formation of radical cations was observed only with anisole and 3-chloroanisole where Cl{sub 2}{sup .-} radical reacts with the higher rates of 3.4 and 2.1 x 10{sup 8} dm{sup 3} mol{sup -1} s{sup -1} respectively. (author). 5 refs., 1 fig.
Authors:
Mudaliar, Mohan; Rao, B S.M.; [1]  Sonntag, C von [2] 
  1. Poona Univ., Pune (India). Dept. of Chemistry
  2. Max-Planck-Institut fuer Strahlenchemie, Muelheim an der Ruhr (Germany)
Publication Date:
Dec 31, 1994
Product Type:
Conference
Report Number:
CONF-9401116-
Reference Number:
SCA: 400600; PA: AIX-26:062482; EDB-95:131109; SN: 95001457652
Resource Relation:
Conference: TRSP-94: Trombay symposium on radiation and photochemistry, Bombay (India), 17-21 Jan 1994; Other Information: PBD: 1994; Related Information: Is Part Of Trombay symposium on radiation and photochemistry. Preprints vol.2: contributed papers; PB: 407 p.
Subject:
40 CHEMISTRY; CHLORINATED AROMATIC HYDROCARBONS; PULSED IRRADIATION; ABSORPTION SPECTRA; ANISOLE; AQUEOUS SOLUTIONS; BENZENE; CHEMICAL REACTION KINETICS; CHLORIDES; OXIDATION; RADICALS
OSTI ID:
100359
Research Organizations:
Department of Atomic Energy, Bombay (India). Board of Research in Nuclear Sciences
Country of Origin:
India
Language:
English
Other Identifying Numbers:
TRN: IN9501078062482
Submitting Site:
INIS
Size:
pp. 4-6
Announcement Date:
Jan 16, 2004

Conference:

Citation Formats

Mudaliar, Mohan, Rao, B S.M., and Sonntag, C von. Radiation chemical oxidation of substituted benzenes by Cl{sub 2}{sup .-}. India: N. p., 1994. Web.
Mudaliar, Mohan, Rao, B S.M., & Sonntag, C von. Radiation chemical oxidation of substituted benzenes by Cl{sub 2}{sup .-}. India.
Mudaliar, Mohan, Rao, B S.M., and Sonntag, C von. 1994. "Radiation chemical oxidation of substituted benzenes by Cl{sub 2}{sup .-}." India.
@misc{etde_100359,
title = {Radiation chemical oxidation of substituted benzenes by Cl{sub 2}{sup .-}}
author = {Mudaliar, Mohan, Rao, B S.M., and Sonntag, C von}
abstractNote = {Reaction of Cl{sub 2}{sup .-} radical with chloro, methyl and methoxylated benzenes was studied by pulse radiolysis in acidic condition. The rate of Cl{sub 2}{sup .-} reaction with chlorobenzene, toluene and chlorotoluene was lower (0.8 - 15 x 10{sup 6} dm{sup 3} mol{sup -1} s{sup -1}), however, formation of radical cations was observed only with anisole and 3-chloroanisole where Cl{sub 2}{sup .-} radical reacts with the higher rates of 3.4 and 2.1 x 10{sup 8} dm{sup 3} mol{sup -1} s{sup -1} respectively. (author). 5 refs., 1 fig.}
place = {India}
year = {1994}
month = {Dec}
}