Abstract
Reaction of Cl{sub 2}{sup .-} radical with chloro, methyl and methoxylated benzenes was studied by pulse radiolysis in acidic condition. The rate of Cl{sub 2}{sup .-} reaction with chlorobenzene, toluene and chlorotoluene was lower (0.8 - 15 x 10{sup 6} dm{sup 3} mol{sup -1} s{sup -1}), however, formation of radical cations was observed only with anisole and 3-chloroanisole where Cl{sub 2}{sup .-} radical reacts with the higher rates of 3.4 and 2.1 x 10{sup 8} dm{sup 3} mol{sup -1} s{sup -1} respectively. (author). 5 refs., 1 fig.
Mudaliar, Mohan;
Rao, B S.M.;
[1]
Sonntag, C von
[2]
- Poona Univ., Pune (India). Dept. of Chemistry
- Max-Planck-Institut fuer Strahlenchemie, Muelheim an der Ruhr (Germany)
Citation Formats
Mudaliar, Mohan, Rao, B S.M., and Sonntag, C von.
Radiation chemical oxidation of substituted benzenes by Cl{sub 2}{sup .-}.
India: N. p.,
1994.
Web.
Mudaliar, Mohan, Rao, B S.M., & Sonntag, C von.
Radiation chemical oxidation of substituted benzenes by Cl{sub 2}{sup .-}.
India.
Mudaliar, Mohan, Rao, B S.M., and Sonntag, C von.
1994.
"Radiation chemical oxidation of substituted benzenes by Cl{sub 2}{sup .-}."
India.
@misc{etde_100359,
title = {Radiation chemical oxidation of substituted benzenes by Cl{sub 2}{sup .-}}
author = {Mudaliar, Mohan, Rao, B S.M., and Sonntag, C von}
abstractNote = {Reaction of Cl{sub 2}{sup .-} radical with chloro, methyl and methoxylated benzenes was studied by pulse radiolysis in acidic condition. The rate of Cl{sub 2}{sup .-} reaction with chlorobenzene, toluene and chlorotoluene was lower (0.8 - 15 x 10{sup 6} dm{sup 3} mol{sup -1} s{sup -1}), however, formation of radical cations was observed only with anisole and 3-chloroanisole where Cl{sub 2}{sup .-} radical reacts with the higher rates of 3.4 and 2.1 x 10{sup 8} dm{sup 3} mol{sup -1} s{sup -1} respectively. (author). 5 refs., 1 fig.}
place = {India}
year = {1994}
month = {Dec}
}
title = {Radiation chemical oxidation of substituted benzenes by Cl{sub 2}{sup .-}}
author = {Mudaliar, Mohan, Rao, B S.M., and Sonntag, C von}
abstractNote = {Reaction of Cl{sub 2}{sup .-} radical with chloro, methyl and methoxylated benzenes was studied by pulse radiolysis in acidic condition. The rate of Cl{sub 2}{sup .-} reaction with chlorobenzene, toluene and chlorotoluene was lower (0.8 - 15 x 10{sup 6} dm{sup 3} mol{sup -1} s{sup -1}), however, formation of radical cations was observed only with anisole and 3-chloroanisole where Cl{sub 2}{sup .-} radical reacts with the higher rates of 3.4 and 2.1 x 10{sup 8} dm{sup 3} mol{sup -1} s{sup -1} respectively. (author). 5 refs., 1 fig.}
place = {India}
year = {1994}
month = {Dec}
}