{
  "date" : "1998-12-01",
  "identifier_doecontract" : "",
  "subject" : "25 ENERGY STORAGE; VANADIUM OXIDES; CATHODES; ELECTRIC BATTERIES; LITHIUM IONS; THIN FILMS; TEXTURE; AMORPHOUS STATE; CHEMICAL VAPOR DEPOSITION; CAPACITY; STABILITY; STRUCTURE FACTORS",
  "description" : "We report on investigations of vanadium oxide thin film cathodes prepared by three different synthesis techniques. Our experimental results on PLD-grown, textured V{sub 2}O{sub 5} crystalline films concur with reports in the literature that there is a voltage threshold above which, cycling appears to be completely reversible and below which, cycling appears to be irreversible. Crystalline films discharged beyond the threshold to 2.0 V exhibited an immediate and continuous fade in capacity as well as a nearly 90% decrease in XRD peak intensity and a similar decrease in Raman signal intensity in as few as ten cycles. PLD-grown amorphous films show capacity loss of <2% over 200 cycles. Amorphous plasma-enhanced chemical vapor deposition (PECVD) films have capacities as high as 1.5 Li/V with excellent stability over 3000 cycles. Solution-grown nanoparticles (<100 nm) of VO{sub 2} were spray-deposited and sintered at relatively low temperatures to produce nanoporous films. Cycling properties along with structural investigations by XRD and Raman scattering will be presented",
  "language" : "English",
  "identifier_report" : "",
  "publisher_sponsor" : "",
  "publisher_country" : "Netherlands",
  "source" : "ECN; SCA: 250903; PA: ECN-99:0E0410; EDB-99:014399; SN: 99002054618",
  "purl" : "",
  "title" : "Next generation V{sub 2}O{sub 5} cathode materials for Li rechargeable batteries",
  "type" : "Journal Article",
  "subject_related" : "",
  "relation" : "Journal Name: Solid State Ionics; Journal Volume: 113-115; Journal Issue: 1-4; Other Information: PBD: 1 Dec 1998",
  "entry_date" : "2010-12-29",
  "subject_list" : [ "25 ENERGY STORAGE", "VANADIUM OXIDES", "CATHODES", "ELECTRIC BATTERIES", "LITHIUM IONS", "THIN FILMS", "TEXTURE", "AMORPHOUS STATE", "CHEMICAL VAPOR DEPOSITION", "CAPACITY", "STABILITY", "STRUCTURE FACTORS" ],
  "publisher_availability" : "",
  "rights" : "",
  "announced_date" : "1999-02-08",
  "type_qualifier" : "",
  "has_fulltext" : false,
  "coverage" : "",
  "identifier" : "",
  "journal_volume" : "113-115",
  "creator" : "McGraw, J M [Colorado School of Mines, Golden, Colorado 80401 (United States)]; Perkins, J D; Zhang, J -G; Liu, P; Parilla, P A; Turner, J; Schulz, D L; Curtis, C J; Ginley, D S [National Renewable Energy Laboratory, Golden, Colorado 80401 (United States)]",
  "site_ownership_code" : "ECN",
  "osti_id" : "302630",
  "journal_issue" : "1-4",
  "resource_type" : "JOUR",
  "format" : "Medium: X; Size: pp. 407-413",
  "journal_name" : [ ],
  "contributing_organizations" : "",
  "citation_location" : "https://www.osti.gov/etdeweb/biblio/302630",
  "publication_year" : 1998,
  "subject_list_commas" : "25 ENERGY STORAGE, VANADIUM OXIDES, CATHODES, ELECTRIC BATTERIES, LITHIUM IONS, THIN FILMS, TEXTURE, AMORPHOUS STATE, CHEMICAL VAPOR DEPOSITION, CAPACITY, STABILITY, STRUCTURE FACTORS",
  "publisher" : "",
  "identifier_other" : "Journal ID: SSIOD3; ISSN 0167-2738; TRN: NL99E0410",
  "publisher_research" : "",
  "creators_list" : [ "McGraw, J M [Colorado School of Mines, Golden, Colorado 80401 (United States)]", "Perkins, J D", "Zhang, J -G", "Liu, P", "Parilla, P A", "Turner, J", "Schulz, D L", "Curtis, C J", "Ginley, D S [National Renewable Energy Laboratory, Golden, Colorado 80401 (United States)]" ],
  "doi" : "https://doi.org/10.1016/S0167-2738(98)00383-X"
}