{
  "date" : "2014-01-01",
  "identifier_doecontract" : "",
  "subject" : "37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; 77 NANOSCIENCE AND NANOTECHNOLOGY; CRYSTALS; DISTRIBUTION; ELECTRODES; EXTRACTION; LITHIUM; LITHIUM IONS; MOLTEN SALTS; NANOPARTICLES; NANOSTRUCTURES; OXIDES; PARTICLE SIZE; SYNTHESIS",
  "description" : "Nanocrystalline Li[Li₀.₂₆Ni₀.₁₁Mn₀.₆₃]O₂ were easily prepared by using Ni₀.₁₅Mn₀.₅(OH)₂ and Li₂CO₃ as precursors and KCl as melt-salt for the high capacity materials of Li-ion storage. The obtained nanoparticles showed same morphology of polygonal shape and the particle size distribution increased with increasing sinter temperature. The Li[Li₀.₂₆Ni₀.₁₁Mn₀.₆₃]O₂ electrode sintered at 800 °C for 12 h exhibits a reversible capacity of more than 300 mAh g⁻¹ at 0.1 C rate between 2 V and 4.8 V and the capacity retention remains 86% and 90% after 90 cycles at the rate of 0.5 C and 1 C, respectively. These superior electrochemical performances are discussed in detail and ascribed to the low dimension and well-crystallized particles. The low dimension provides a short diffusion path and fast transport channels for the lithium ion insertion/extraction reactions and the well-crystallized structure restrains the elimination of oxide ion vacancies and metal ions rearrangement during charge–discharge cycling.",
  "language" : "English",
  "identifier_report" : "",
  "publisher_sponsor" : "",
  "publisher_country" : "United Kingdom",
  "source" : "INIS",
  "purl" : "",
  "title" : "The Enhanced Electrochemical Performance of Nanocrystalline Li[Li₀.₂₆Ni₀.₁₁Mn₀.₆₃]O₂ Synthesized by the Molten-Salt Method for Li-ion batteries",
  "type" : "Journal Article",
  "subject_related" : "",
  "relation" : "Journal Name: Electrochimica Acta; Journal Volume: 117; Other Information: Copyright (c) 2013 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)",
  "entry_date" : "2015-05-05",
  "subject_list" : [ "37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY", "77 NANOSCIENCE AND NANOTECHNOLOGY", "CRYSTALS", "DISTRIBUTION", "ELECTRODES", "EXTRACTION", "LITHIUM", "LITHIUM IONS", "MOLTEN SALTS", "NANOPARTICLES", "NANOSTRUCTURES", "OXIDES", "PARTICLE SIZE", "SYNTHESIS" ],
  "publisher_availability" : "Available from http://dx.doi.org/10.1016/j.electacta.2013.11.124",
  "rights" : "",
  "announced_date" : "2015-04-03",
  "type_qualifier" : "",
  "has_fulltext" : false,
  "coverage" : "",
  "identifier" : "PII: S0013-4686(13)02357-8",
  "journal_volume" : "117",
  "creator" : "ZhenYao, Wang; Biao, Li; Jin, Ma; DingGuo, Xia",
  "site_ownership_code" : "INIS",
  "osti_id" : "22321859",
  "journal_issue" : "",
  "resource_type" : "JOUR",
  "format" : "Medium: X; Size: page(s) 285-291",
  "journal_name" : [ ],
  "contributing_organizations" : "",
  "citation_location" : "https://www.osti.gov/etdeweb/biblio/22321859",
  "publication_year" : 2014,
  "subject_list_commas" : "37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY, 77 NANOSCIENCE AND NANOTECHNOLOGY, CRYSTALS, DISTRIBUTION, ELECTRODES, EXTRACTION, LITHIUM, LITHIUM IONS, MOLTEN SALTS, NANOPARTICLES, NANOSTRUCTURES, OXIDES, PARTICLE SIZE, SYNTHESIS",
  "publisher" : "",
  "identifier_other" : "Journal ID: ISSN 0013-4686; CODEN: ELCAAV; Other: PII: S0013-4686(13)02357-8; TRN: GB15R1009028068",
  "publisher_research" : "",
  "creators_list" : [ "ZhenYao, Wang", "Biao, Li", "Jin, Ma", "DingGuo, Xia" ],
  "doi" : "https://doi.org/10.1016/J.ELECTACTA.2013.11.124"
}