{
  "date" : "2013-03-01",
  "identifier_doecontract" : "",
  "subject" : "37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; ANODES; CONGLOMERATES; COPPER; COPPER PHOSPHIDES; DEPOSITS; ELECTRIC BATTERIES; ELECTRODEPOSITION; ENERGY DENSITY; ENERGY STORAGE; HYBRIDIZATION; LITHIUM IONS; MICROSTRUCTURE; OXIDATION; PHOSPHORUS; SCANNING ELECTRON MICROSCOPY; SOLIDS; X-RAY DIFFRACTION",
  "description" : "Air stable copper phosphide of thicknesses (0.2, 0.4 μm) was synthesized over copper plates (of 10 mm diameter) by hybrid electrochemical deposition and low temperature solid-state reaction. Stoichiometric amount of red phosphorus (P) were sprayed over electrodeposited copper and followed by annealing at 250 °C under inert gas atmosphere for different durations (5 h, 7 h and 12 h). During this process, phosphorus particles diffuse by excavating into the copper deposits, producing holes, where the Cu{sub 3}P crystallites nucleate and lead to conglomeration of several agglomerates and hence resulted in non-homogeneous morphology. A small extend of Cu{sub 3}P oxidation occurs over the film's top surface. X-ray diffraction (XRD) patterns confirm that the layer to be pure Cu{sub 3}P. Scanning electron microscopy (FEG-SEM) reveals a porous microstructure consisting of agglomerated particles with ∼10 μm size. The as-prepared carbon-free Cu{sub 3}P electrodes exhibited significantly improved capacity retention and rate capability characteristics over 40 cycles when electrochemically tested against lithium at constant 20 μA/cm{sup 2} rendering it as possible negative electrode for high energy density lithium-ion battery (LiB) applications.",
  "language" : "English",
  "identifier_report" : "",
  "publisher_sponsor" : "",
  "publisher_country" : "United Kingdom",
  "source" : "INIS",
  "purl" : "",
  "title" : "Thin copper phosphide films as conversion anode for lithium-ion battery applications",
  "type" : "Journal Article",
  "subject_related" : "",
  "relation" : "Journal Name: Electrochimica Acta; Journal Volume: 92; Other Information: Copyright (c) 2013 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)",
  "entry_date" : "2014-06-12",
  "subject_list" : [ "37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY", "ANODES", "CONGLOMERATES", "COPPER", "COPPER PHOSPHIDES", "DEPOSITS", "ELECTRIC BATTERIES", "ELECTRODEPOSITION", "ENERGY DENSITY", "ENERGY STORAGE", "HYBRIDIZATION", "LITHIUM IONS", "MICROSTRUCTURE", "OXIDATION", "PHOSPHORUS", "SCANNING ELECTRON MICROSCOPY", "SOLIDS", "X-RAY DIFFRACTION" ],
  "publisher_availability" : "Available from http://dx.doi.org/10.1016/j.electacta.2012.12.136",
  "rights" : "",
  "announced_date" : "2014-06-12",
  "type_qualifier" : "",
  "has_fulltext" : false,
  "coverage" : "",
  "identifier" : "PII: S0013-4686(13)00021-2",
  "journal_volume" : "92",
  "creator" : "Chandrasekar, M. S. [Electrochemical Energy Laboratory, Department of Energy Science and Engineering, Indian Institute of Technology Bombay, Mumbai 400076 (India)]; Mitra, Sagar [Electrochemical Energy Laboratory, Department of Energy Science and Engineering, Indian Institute of Technology Bombay, Mumbai 400076 (India)]",
  "site_ownership_code" : "INIS",
  "osti_id" : "22238674",
  "journal_issue" : "",
  "resource_type" : "JOUR",
  "format" : "Medium: X; Size: page(s) 47-54",
  "journal_name" : [ ],
  "contributing_organizations" : "",
  "citation_location" : "https://www.osti.gov/etdeweb/biblio/22238674",
  "publication_year" : 2013,
  "subject_list_commas" : "37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY, ANODES, CONGLOMERATES, COPPER, COPPER PHOSPHIDES, DEPOSITS, ELECTRIC BATTERIES, ELECTRODEPOSITION, ENERGY DENSITY, ENERGY STORAGE, HYBRIDIZATION, LITHIUM IONS, MICROSTRUCTURE, OXIDATION, PHOSPHORUS, SCANNING ELECTRON MICROSCOPY, SOLIDS, X-RAY DIFFRACTION",
  "publisher" : "",
  "identifier_other" : "Journal ID: ISSN 0013-4686; CODEN: ELCAAV; Other: PII: S0013-4686(13)00021-2; TRN: GB14R4056059763",
  "publisher_research" : "",
  "creators_list" : [ "Chandrasekar, M. S. [Electrochemical Energy Laboratory, Department of Energy Science and Engineering, Indian Institute of Technology Bombay, Mumbai 400076 (India)]", "Mitra, Sagar [Electrochemical Energy Laboratory, Department of Energy Science and Engineering, Indian Institute of Technology Bombay, Mumbai 400076 (India)]" ],
  "doi" : "https://doi.org/10.1016/J.ELECTACTA.2012.12.136"
}