%A"Jambon, C" %D1962 %I; Commissariat a l'Energie Atomique. Centre d'Etudes Nucleaires de Saclay, 91 - Gif-sur-Yvette (France) %2 %J[] %K37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY, BOND LENGTHS, CHEMICAL PREPARATION, CHEMICAL REACTION KINETICS, DEHALOGENATION, DEUTERIUM, ISOTOPE EFFECTS, SOLVOLYSIS %PMedium: ED; Size: 42 pages %TDeuterium isotopic effects connected with unimolecular and concerted mechanisms. The case of 1-deutero-2-chloro alcohols; Effets isotopiques du deuterium attaches a des mecanismes unimoleculaires et concertes. Cas des deutero-1-chloro-2 alcools %XAfter a bibliographic analysis of the probable causes of isotopic effects and their comparison, with the simplifications provided by the athermal model, a discussion of the isotopic effect of deuterium in organic molecules in terms of structural influences is presented, showing the important role of the C-D bond length which is shorter than the C-H bond length, and of the D atom's Van der Waals radius, shorter than that of the H atom. Kinetic measurements were carried out on some reactions involving the mechanisms proposed: unimolecular ionizations and halogen concentrates. The structural models chosen are: 2-chloro-cyclo-hexanols cis and trans 1-H and 2-D; 2-chloro-cyclo-pentanols cis trans 1-H and 1-D; 1-phenyl-l-chloro-2-propanol threo 2-H and 2-D. (author) [French] Apres une analyse bibliographique des causes probables d'effets isotopiques et leur comparaison, avec les simplifications qu'apporte le modele athermique, on a entrepris l'etude de la discussion isotopique du deuterium dans des molecules organiques en termes d'influences structurelles, cherchant a degager le role important de la longueur de la liaison C-D plus courte que C-H, et du rayon de Van der Waals de l'atome de D plus petit que celui de H. On a effectue des mesures cinetiques sur quelques reactions invoquant les mecanismes envisages: ionisations unimoleculaires et concentrees d'halogenes. Les modeles structuraux choisis sont: chloro 2 - cyclohexanols cis et trans H 1 et D 1; chloro 2 - cyclopentanols cis et trans H 1 et D 1; phenyl 1 - chloro 1 - propanol 2 threo H 2 et D 2. (auteur) %0Technical Report %NCEA-R-2221;TRN: FR04R2221044226 %1 %CFrance %Rhttps://doi.org/ TRN: FR04R2221044226 FRN %GFrench