{
  "date" : "1995-04-01",
  "identifier_doecontract" : "",
  "subject" : "25 ENERGY STORAGE; MOLYBDENUM OXIDES; LITHIUM COMPOUNDS; SODIUM COMPOUNDS; MAGNESIUM COMPOUNDS; ELECTROCHEMISTRY; ELECTRODES; CARBONIC ACID ESTERS; ELECTROLYTES; MOLTEN SALTS; CHLORIDES; ACETONITRILE; PERCHLORATES; ELECTRIC BATTERIES",
  "description" : "The electrochemical insertion of divalent magnesium cations into orthorhombic molybdenum(VI) oxide was studied with regard to their use as electroactive species in ion-transfer battery systems and compared to the insertion of Li{sup +} and Na{sup +}. Specific charges of up to 300 and 240 Ah kg{sup -1} were obtained in organic, propylene carbonate-based electrolytes for the lithium and sodium insertion, respectively, in the first reduction half-cycle. Reversible Mg{sup 2+} insertion could be demonstrated in a room temperature molten salt electrolyte consisting of 3 wt.% MgCl{sub 2}, 41 wt.% 1-ethyl-3-methylimidazolium chloride, and 56 wt.% AlCl{sub 3}. Specific charges of up to 160 Ah kg{sup -1} were obtained with MoO{sub 3} in the first reduction half-cycle. The Mg{sup 2+} insertion process can be enhanced using an organic electrolyte with traces of H{sub 2}O. In 1 M Mg(ClO{sub 4}){sub 2}/acetonitrile with 3 mol% of H{sub 2}O, specific charges of up to 210 Ah kg{sup -1} were measured in the first reduction. (orig.)",
  "language" : "English",
  "identifier_report" : "CONF-940568-",
  "publisher_sponsor" : "",
  "publisher_country" : "Switzerland",
  "source" : "CHF; SCA: 250903; PA: CHF-95:0GI342; EDB-95:147762; SN: 95001456397",
  "purl" : "",
  "title" : "Electrochemical insertion of lithium, sodium, and magnesium in molybdenum(VI) oxide",
  "type" : "Journal Article",
  "subject_related" : "",
  "relation" : "Journal Name: Journal of Power Sources; Journal Volume: 54; Journal Issue: 2; Conference: 7. international meeting on lithium batteries (IMLB-7), Cambridge, MA (United States), 15-20 May 1994; Other Information: PBD: Apr 1995",
  "entry_date" : "2010-12-29",
  "subject_list" : [ "25 ENERGY STORAGE", "MOLYBDENUM OXIDES", "LITHIUM COMPOUNDS", "SODIUM COMPOUNDS", "MAGNESIUM COMPOUNDS", "ELECTROCHEMISTRY", "ELECTRODES", "CARBONIC ACID ESTERS", "ELECTROLYTES", "MOLTEN SALTS", "CHLORIDES", "ACETONITRILE", "PERCHLORATES", "ELECTRIC BATTERIES" ],
  "publisher_availability" : "",
  "rights" : "",
  "announced_date" : "1995-11-27",
  "type_qualifier" : "",
  "has_fulltext" : false,
  "coverage" : "",
  "identifier" : "",
  "journal_volume" : "54",
  "creator" : "Spahr, M E [Paul Scherrer Inst., Electrochemistry Section, Villigen PSI (Switzerland)]; Novak, P [Paul Scherrer Inst., Electrochemistry Section, Villigen PSI (Switzerland)]; Haas, O [Paul Scherrer Inst., Electrochemistry Section, Villigen PSI (Switzerland)]; Nesper, R [Swiss Federal Inst. of Tech. (ETH), Lab. for Inorganic Chemistry, Zurich (Switzerland)]",
  "site_ownership_code" : "CHF",
  "osti_id" : "123048",
  "journal_issue" : "2",
  "resource_type" : "JOUR",
  "format" : "Medium: X; Size: pp. 346-351",
  "journal_name" : [ ],
  "contributing_organizations" : "",
  "citation_location" : "https://www.osti.gov/etdeweb/biblio/123048",
  "publication_year" : 1995,
  "subject_list_commas" : "25 ENERGY STORAGE, MOLYBDENUM OXIDES, LITHIUM COMPOUNDS, SODIUM COMPOUNDS, MAGNESIUM COMPOUNDS, ELECTROCHEMISTRY, ELECTRODES, CARBONIC ACID ESTERS, ELECTROLYTES, MOLTEN SALTS, CHLORIDES, ACETONITRILE, PERCHLORATES, ELECTRIC BATTERIES",
  "publisher" : "",
  "identifier_other" : "Journal ID: JPSODZ; ISSN 0378-7753; TRN: CH95GI342",
  "publisher_research" : "",
  "creators_list" : [ "Spahr, M E [Paul Scherrer Inst., Electrochemistry Section, Villigen PSI (Switzerland)]", "Novak, P [Paul Scherrer Inst., Electrochemistry Section, Villigen PSI (Switzerland)]", "Haas, O [Paul Scherrer Inst., Electrochemistry Section, Villigen PSI (Switzerland)]", "Nesper, R [Swiss Federal Inst. of Tech. (ETH), Lab. for Inorganic Chemistry, Zurich (Switzerland)]" ],
  "doi" : "https://doi.org/10.1016/0378-7753(94)02099-O"
}