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Title: Method for identifying and probing phase transitions in materials

Abstract

The present invention includes a method for identifying and probing phase transitions in materials. A polymorphic material capable of existing in at least one non-centrosymmetric phase is interrogated with a beam of laser light at a chosen wavelength and frequency. A phase transition is induced in the material while it is interrogated. The intensity of light scattered by the material and having a wavelength equal to one half the wavelength of the interrogating laser light is detected. If the phase transition results in the production of a non-centrosymmetric phase, the intensity of this scattered light increases; if the phase transition results in the disappearance of a non-centrosymmetric phase, the intensity of this scattered light decreases.

Inventors:
 [1];  [1];  [1];  [1];  [1];  [1]
  1. Los Alamos, NM
Issue Date:
Research Org.:
Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
OSTI Identifier:
874805
Patent Number(s):
6465255
Assignee:
The Regents of the University of California (Los Alamos, NM)
Patent Classifications (CPCs):
G - PHYSICS G01 - MEASURING G01N - INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
DOE Contract Number:  
W-7405-ENG-36
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
method; identifying; probing; phase; transitions; materials; polymorphic; material; capable; existing; non-centrosymmetric; interrogated; beam; laser; light; chosen; wavelength; frequency; transition; induced; intensity; scattered; equal; half; interrogating; detected; results; production; increases; disappearance; decreases; laser light; phase transition; /436/252/356/

Citation Formats

Asay, Blaine W, Henson, Bryan F, Sander, Robert K, Robinson, Jeanne M, Son, Steven F, and Dickson, Peter M. Method for identifying and probing phase transitions in materials. United States: N. p., 2002. Web.
Asay, Blaine W, Henson, Bryan F, Sander, Robert K, Robinson, Jeanne M, Son, Steven F, & Dickson, Peter M. Method for identifying and probing phase transitions in materials. United States.
Asay, Blaine W, Henson, Bryan F, Sander, Robert K, Robinson, Jeanne M, Son, Steven F, and Dickson, Peter M. Tue . "Method for identifying and probing phase transitions in materials". United States. https://www.osti.gov/servlets/purl/874805.
@article{osti_874805,
title = {Method for identifying and probing phase transitions in materials},
author = {Asay, Blaine W and Henson, Bryan F and Sander, Robert K and Robinson, Jeanne M and Son, Steven F and Dickson, Peter M},
abstractNote = {The present invention includes a method for identifying and probing phase transitions in materials. A polymorphic material capable of existing in at least one non-centrosymmetric phase is interrogated with a beam of laser light at a chosen wavelength and frequency. A phase transition is induced in the material while it is interrogated. The intensity of light scattered by the material and having a wavelength equal to one half the wavelength of the interrogating laser light is detected. If the phase transition results in the production of a non-centrosymmetric phase, the intensity of this scattered light increases; if the phase transition results in the disappearance of a non-centrosymmetric phase, the intensity of this scattered light decreases.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Jan 01 00:00:00 EST 2002},
month = {Tue Jan 01 00:00:00 EST 2002}
}

Works referenced in this record:

Polymorphs of Tamoxifen Citrate: Detailed Structural Characterization of the Stable Form
journal, March 1987


Quantitative Measurements of Multilayer Physical Adsorption on Heterogeneous Surfaces from Nonlinear Light Scattering
journal, August 1997


Dynamic Observation of a Thermally Activated Structure Change in 1,3,5-Triamino-2,4,6-trinitrobenzene (TATB) by Second Harmonic Generation
journal, July 1999


Application of solid-phase transition kinetics to the properties of HMX
journal, February 1983