Selective thermal and photooxidation of hydrocarbons in zeolites by oxygen
Abstract
A process for a combined selective thermal oxidation and photooxidation of hydrocarbons adsorbed onto zeolite matrices. A highly combined selective thermal oxidation and photooxidation of unsubstituted or alkyl substituted alkanes, alkenes, aromatics and cycloalkyls in solvent free zeolites under dark thermal conditions or under irradiation with visible light. The process oxidizes hydrocarbons almost completely selectively without substantial production of byproducts.
- Inventors:
-
- Berkeley, CA
- Basel, CH
- Saint Charles, MO
- Issue Date:
- Research Org.:
- Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- OSTI Identifier:
- 874164
- Patent Number(s):
- 6329553
- Assignee:
- The Regents of the University of California (Oakland, CA)
- Patent Classifications (CPCs):
-
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07B - GENERAL METHODS OF ORGANIC CHEMISTRY
- DOE Contract Number:
- AC03-76SF00098
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- selective; thermal; photooxidation; hydrocarbons; zeolites; oxygen; process; combined; oxidation; adsorbed; zeolite; matrices; highly; unsubstituted; alkyl; substituted; alkanes; alkenes; aromatics; cycloalkyls; solvent; free; dark; conditions; irradiation; visible; light; oxidizes; completely; selectively; substantial; production; byproducts; visible light; thermal oxidation; /999/204/210/
Citation Formats
Frei, Heinz, Blatter, Fritz, and Sun, Hai. Selective thermal and photooxidation of hydrocarbons in zeolites by oxygen. United States: N. p., 2001.
Web.
Frei, Heinz, Blatter, Fritz, & Sun, Hai. Selective thermal and photooxidation of hydrocarbons in zeolites by oxygen. United States.
Frei, Heinz, Blatter, Fritz, and Sun, Hai. Mon .
"Selective thermal and photooxidation of hydrocarbons in zeolites by oxygen". United States. https://www.osti.gov/servlets/purl/874164.
@article{osti_874164,
title = {Selective thermal and photooxidation of hydrocarbons in zeolites by oxygen},
author = {Frei, Heinz and Blatter, Fritz and Sun, Hai},
abstractNote = {A process for a combined selective thermal oxidation and photooxidation of hydrocarbons adsorbed onto zeolite matrices. A highly combined selective thermal oxidation and photooxidation of unsubstituted or alkyl substituted alkanes, alkenes, aromatics and cycloalkyls in solvent free zeolites under dark thermal conditions or under irradiation with visible light. The process oxidizes hydrocarbons almost completely selectively without substantial production of byproducts.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Mon Jan 01 00:00:00 EST 2001},
month = {Mon Jan 01 00:00:00 EST 2001}
}
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Works referenced in this record:
Very strong stabilization of alkene.cntdot.O2 charge-transfer state in zeolite NaY: red-light-induced photooxidation of 2,3-dimethyl-2-butene
journal, August 1993
- Blatter, Fritz; Frei, Heinz
- Journal of the American Chemical Society, Vol. 115, Issue 16
Selective Photooxidation of Small Alkenes by O2 with Red Light in Zeolite Y
journal, March 1994
- Blatter, Fritz; Frei, Heinz
- Journal of the American Chemical Society, Vol. 116, Issue 5
Diffuse Reflectance Spectroscopy of Visible Alkene.O2 Charge-Transfer Absorptions in Zeolite Y and Determination of Photooxygenation Quantum Efficiencies
journal, December 1994
- Blatter, Fritz; Moreau, Frederick; Frei, Heinz
- The Journal of Physical Chemistry, Vol. 98, Issue 50