Solid polymer electrolyte compositions

Garbe, James E; Atanasoski, Radoslav; Hamrock, Steven J; Le, Dinh Ba

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Title: Solid polymer electrolyte compositions

Abstract

An electrolyte composition is featured that includes a solid, ionically conductive polymer, organically modified oxide particles that include organic groups covalently bonded to the oxide particles, and an alkali metal salt. The electrolyte composition is free of lithiated zeolite. The invention also features cells that incorporate the electrolyte composition.

Inventors:

Garbe, James E ^[1]; Atanasoski, Radoslav ^[2]; Hamrock, Steven J ^[3]; Le, Dinh Ba ^[3]

Stillwater, MN
Edina, MN
St. Paul, MN

Issue Date:: Mon Jan 01 00:00:00 EST 2001

Research Org.:: United States Advanced Battery Consortium, Dearborn, MI (US)

OSTI Identifier:: 874117

Patent Number(s):: 6316149

Assignee:: Minnesota Mining and Manufacturing (St. Paul, MN); Hydro-Quebec Corporation (Montreal, CA)

Patent Classifications (CPCs):: H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01B - CABLES

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY

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H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01B - CABLES
H01B1/122 - {Ionic conductors}

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M10/052 - Li-accumulators
H01M10/0565 - Polymeric materials, e.g. gel-type or solid-type
H01M4/13 - Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators
H01M4/62 - Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
H01M4/621 - {Binders}
H01M6/168 - {by additives}

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E60/10 - Energy storage

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DOE Contract Number:: FC02-91CE50336

Resource Type:: Patent

Country of Publication:: United States

Language:: English

Subject:: solid; polymer; electrolyte; compositions; composition; featured; ionically; conductive; organically; modified; oxide; particles; organic; covalently; bonded; alkali; metal; salt; free; lithiated; zeolite; features; cells; incorporate; alkali metal; solid polymer; polymer electrolyte; metal salt; electrolyte composition; covalently bonded; ionically conductive; oxide particle; /429/

Citation Formats


                    Garbe, James E, Atanasoski, Radoslav, Hamrock, Steven J, and Le, Dinh Ba. Solid polymer electrolyte compositions.  United States: N. p., 2001. 
        Web.

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                    Garbe, James E, Atanasoski, Radoslav, Hamrock, Steven J, & Le, Dinh Ba. Solid polymer electrolyte compositions.  United States.

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                    Garbe, James E, Atanasoski, Radoslav, Hamrock, Steven J, and Le, Dinh Ba. Mon .  
        "Solid polymer electrolyte compositions".  United States.  https://www.osti.gov/servlets/purl/874117.

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@article{osti_874117,

  title        = {Solid polymer electrolyte compositions},

  author       = {Garbe, James E and Atanasoski, Radoslav and Hamrock, Steven J and Le, Dinh Ba},

  abstractNote = {An electrolyte composition is featured that includes a solid, ionically conductive polymer, organically modified oxide particles that include organic groups covalently bonded to the oxide particles, and an alkali metal salt. The electrolyte composition is free of lithiated zeolite. The invention also features cells that incorporate the electrolyte composition.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {Mon Jan 01 00:00:00 EST 2001},

  month        = {Mon Jan 01 00:00:00 EST 2001}

}

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Works referenced in this record:

Composite Electrolytes Prepared from Fumed Silica, Polyethylene Oxide Oligomers, and Lithium Salts
journal, February 1997

Fan, Jiang; Fedkiw, Peter S.
Journal of The Electrochemical Society, Vol. 144, Issue 2
https://doi.org/10.1149/1.1837423

Composite polymer electrolytes using surface-modified fumed silicas: conductivity and rheology
journal, August 1998

Fan, Jiang; Raghavan, Srinivasa R.; Yu, Xi-Yun
Solid State Ionics, Vol. 111, Issue 1-2
https://doi.org/10.1016/S0167-2738(98)00151-9

Composite Polymer Electrolytes Using Fumed Silica Fillers: Rheology and Ionic Conductivity
journal, December 1994

Khan, Saad A.; Baker, Gregory L.; Colson, Sandrine
Chemistry of Materials, Vol. 6, Issue 12
https://doi.org/10.1021/cm00048a023

Kinetics and stability of the lithium electrode in poly(methylmethacrylate)-based gel electrolytes
journal, June 1995

Appetecchi, G. B.; Croce, F.; Scrosati, B.
Electrochimica Acta, Vol. 40, Issue 8
https://doi.org/10.1016/0013-4686(94)00345-2

Dynamic rheological behavior of flocculated fumed silica suspensions
journal, November 1993

Khan, Saad A.; Zoeller, Nancy J.
Journal of Rheology, Vol. 37, Issue 6
https://doi.org/10.1122/1.550378

Properties and potential application of silica-gelled electrolytes for lithium-ion batteries
journal, October 1997

Eichinger, G.; Fabian, M.
Journal of Power Sources, Vol. 68, Issue 2
https://doi.org/10.1016/S0378-7753(97)02589-5

Electrochemical Properties of Polyethylene Oxide-Li[(CF[sub 3]SO[sub 2])[sub 2]N]-Gamma-LiAlO[sub 2] Composite Polymer Electrolytes
journal, January 1995

Borghini, Maria Chiara
Journal of The Electrochemical Society, Vol. 142, Issue 7
https://doi.org/10.1149/1.2044260

Nonaqueous electrolyte solutions: New materials for devices and processes based on recent applied research
journal, January 1995

Gores, H. J.; Barthel, J. M. G.
Pure and Applied Chemistry, Vol. 67, Issue 6
https://doi.org/10.1351/pac199567060919

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Similar Records

Title: Solid polymer electrolyte compositions

Abstract

Citation Formats

Composite Electrolytes Prepared from Fumed Silica, Polyethylene Oxide Oligomers, and Lithium Salts journal, February 1997

Composite polymer electrolytes using surface-modified fumed silicas: conductivity and rheology journal, August 1998

Composite Polymer Electrolytes Using Fumed Silica Fillers: Rheology and Ionic Conductivity journal, December 1994

Kinetics and stability of the lithium electrode in poly(methylmethacrylate)-based gel electrolytes journal, June 1995

Dynamic rheological behavior of flocculated fumed silica suspensions journal, November 1993

Properties and potential application of silica-gelled electrolytes for lithium-ion batteries journal, October 1997

Electrochemical Properties of Polyethylene Oxide-Li[(CF[sub 3]SO[sub 2])[sub 2]N]-Gamma-LiAlO[sub 2] Composite Polymer Electrolytes journal, January 1995

Nonaqueous electrolyte solutions: New materials for devices and processes based on recent applied research journal, January 1995

Composite Electrolytes Prepared from Fumed Silica, Polyethylene Oxide Oligomers, and Lithium Salts
journal, February 1997

Composite polymer electrolytes using surface-modified fumed silicas: conductivity and rheology
journal, August 1998

Composite Polymer Electrolytes Using Fumed Silica Fillers: Rheology and Ionic Conductivity
journal, December 1994

Kinetics and stability of the lithium electrode in poly(methylmethacrylate)-based gel electrolytes
journal, June 1995

Dynamic rheological behavior of flocculated fumed silica suspensions
journal, November 1993

Properties and potential application of silica-gelled electrolytes for lithium-ion batteries
journal, October 1997

Electrochemical Properties of Polyethylene Oxide-Li[(CF[sub 3]SO[sub 2])[sub 2]N]-Gamma-LiAlO[sub 2] Composite Polymer Electrolytes
journal, January 1995

Nonaqueous electrolyte solutions: New materials for devices and processes based on recent applied research
journal, January 1995