Method for the preparation of nanocrystalline diamond thin films
Abstract
A method and system for manufacturing nanocrystalline diamond film on a substrate such as field emission tips. The method involves forming a carbonaceous vapor, providing a gas stream of argon, hydrocarbon and possibly hydrogen, and combining the gas with the carbonaceous vapor, passing the combined carbonaceous vapor and gas carrier stream into a chamber, forming a plasma in the chamber causing fragmentation of the carbonaceous vapor and deposition of a diamond film on the field emission tip.
- Inventors:
-
- Downers Grove, IL
- Naperville, IL
- Issue Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- OSTI Identifier:
- 871657
- Patent Number(s):
- 5772760
- Assignee:
- University Of Chicago (Chicago, IL)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C - CHEMISTRY C23 - COATING METALLIC MATERIAL C23C - COATING METALLIC MATERIAL
- DOE Contract Number:
- W-31109-ENG-38
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- method; preparation; nanocrystalline; diamond; films; manufacturing; film; substrate; field; emission; tips; involves; forming; carbonaceous; vapor; providing; gas; stream; argon; hydrocarbon; possibly; hydrogen; combining; passing; combined; carrier; chamber; plasma; causing; fragmentation; deposition; tip; method involves; gas stream; field emission; diamond film; involves forming; carbonaceous vapor; carrier stream; causing fragmentation; chamber causing; nanocrystalline diamond; method involve; gas carrier; emission tips; /117/427/
Citation Formats
Gruen, Dieter M, and Krauss, Alan R. Method for the preparation of nanocrystalline diamond thin films. United States: N. p., 1998.
Web.
Gruen, Dieter M, & Krauss, Alan R. Method for the preparation of nanocrystalline diamond thin films. United States.
Gruen, Dieter M, and Krauss, Alan R. Tue .
"Method for the preparation of nanocrystalline diamond thin films". United States. https://www.osti.gov/servlets/purl/871657.
@article{osti_871657,
title = {Method for the preparation of nanocrystalline diamond thin films},
author = {Gruen, Dieter M and Krauss, Alan R},
abstractNote = {A method and system for manufacturing nanocrystalline diamond film on a substrate such as field emission tips. The method involves forming a carbonaceous vapor, providing a gas stream of argon, hydrocarbon and possibly hydrogen, and combining the gas with the carbonaceous vapor, passing the combined carbonaceous vapor and gas carrier stream into a chamber, forming a plasma in the chamber causing fragmentation of the carbonaceous vapor and deposition of a diamond film on the field emission tip.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Jun 30 00:00:00 EDT 1998},
month = {Tue Jun 30 00:00:00 EDT 1998}
}
Works referenced in this record:
Near specular reflection of C60 ions in collisions with an HOPG graphite surface
journal, December 1991
- Busmann, H. -G.; Lill, Th.; Hertel, I. V.
- Chemical Physics Letters, Vol. 187, Issue 5
First easily reproduced solution-phase synthesis and confirmation of superconductivity in the fullerene KxC60 (Tc = 18.0 .+-. 0.1 K)
journal, July 1991
- Wang, H. Hau; Kini, Aravinda M.; Savall, Brad M.
- Inorganic Chemistry, Vol. 30, Issue 14
Nucleation of diamond films on surfaces using carbon clusters
journal, December 1991
- Meilunas, R. J.; Chang, R. P. H.; Liu, Shengzhong
- Applied Physics Letters, Vol. 59, Issue 26
Metastable Growth of Diamond and Diamond-Like Phases
journal, August 1991
- Angus, J. C.; Wang, Y.; Sunkara, M.
- Annual Review of Materials Science, Vol. 21, Issue 1
Crushing C60 to diamond at room temperature
journal, January 1992
- Regueiro, Manual Núñez; Monceau, Pierre; Hodeau, Jean-Louis
- Nature, Vol. 355, Issue 6357
Growth mechanism of vapor-deposited diamond
journal, February 1988
- Frenklach, Michael; Spear, Karl E.
- Journal of Materials Research, Vol. 3, Issue 1
C60: Buckminsterfullerene
journal, September 1991
- Kroto, H. W.; Allaf, A. W.; Balm, S. P.
- Chemical Reviews, Vol. 91, Issue 6
Superconductivity at 28.6 K in a rubidium-C60 fullerene compound, RbxC60, synthesized by a solution-phase technique
journal, July 1991
- Wang, H. Hau; Kini, Aravinda M.; Savall, Brad M.
- Inorganic Chemistry, Vol. 30, Issue 15
Laser deposition of carbon clusters on surfaces: A new approach to the study of Fullerenes
journal, December 1990
- Meijer, Gerard; Bethune, Donald S.
- The Journal of Chemical Physics, Vol. 93, Issue 11
Fullerenes
journal, October 1991
- Curl, Robert F.; Smalley, Richard E.
- Scientific American, Vol. 265, Issue 4
Delayed electron emission from photoexcited C 60
journal, November 1991
- Wurz, Peter; Lykke, Keith R.
- The Journal of Chemical Physics, Vol. 95, Issue 9
Diamond Film Semiconductors
journal, October 1992
- Geis, Michael W.; Angus, John C.
- Scientific American, Vol. 267, Issue 4
Fabrication and Characterization of Diamond-Clad Silicon Field Emitter Arrays
journal, December 1995
- Cheng, Huang-Chung; Ku, Tzu-Kun; Hsieh, Biing-Bang
- Japanese Journal of Applied Physics, Vol. 34, Issue Part 1, No. 12B
Resilience of all-carbon molecules C60, C70, and C84: a surface-scattering time-of-flight investigation
journal, October 1991
- Beck, Rainer D.; St. John, Pamela; Alvarez, Marcos M.
- The Journal of Physical Chemistry, Vol. 95, Issue 21
Solid C60: a new form of carbon
journal, September 1990
- Krätschmer, W.; Lamb, Lowell D.; Fostiropoulos, K.
- Nature, Vol. 347, Issue 6291